Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes

碩士 === 國立屏東教育大學 === 化學生物系 === 100 === A series of cyclometalated iridium(III) complexes composed of various benzoxazole derivative and ancillary ligand have been successfully synthesized and fully characterized by 1H NMR, 13C NMR, elemental analyses, and FAB-MS spectrometry after purifying; and most...

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Main Authors:	Pei-chun Liu, 劉珮君
Other Authors:	Tsun-Ren Chen
Format:	Others
Language:	zh-TW
Published:	2012
Online Access:	http://ndltd.ncl.edu.tw/handle/74803723769333787189

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spelling	ndltd-TW-100NPTT51080032015-10-13T21:12:27Z http://ndltd.ncl.edu.tw/handle/74803723769333787189 Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes 銥金屬錯合物之合成、結構與催化特性 Pei-chun Liu 劉珮君碩士國立屏東教育大學化學生物系 100 A series of cyclometalated iridium(III) complexes composed of various benzoxazole derivative and ancillary ligand have been successfully synthesized and fully characterized by 1H NMR, 13C NMR, elemental analyses, and FAB-MS spectrometry after purifying; and most of these complexes were characterized by a single-crystal X-ray analysis. These complexes could be used as catalysts to directly transform aromatic hydrocarbons into aldehydes with very high conversion yield and throughput. The turnovers of the catalytic cycle using these kinds of catalyst are quite high, up to 4000 within 6 hours at low temperature atmospheric pressure. These kinds of complexes could be the promising materials for industrial chemistry to produce aromatic aldehydes or ketones. Tsun-Ren Chen 陳存仁 2012 學位論文 ; thesis 208 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立屏東教育大學 === 化學生物系 === 100 === A series of cyclometalated iridium(III) complexes composed of various benzoxazole derivative and ancillary ligand have been successfully synthesized and fully characterized by 1H NMR, 13C NMR, elemental analyses, and FAB-MS spectrometry after purifying; and most of these complexes were characterized by a single-crystal X-ray analysis. These complexes could be used as catalysts to directly transform aromatic hydrocarbons into aldehydes with very high conversion yield and throughput. The turnovers of the catalytic cycle using these kinds of catalyst are quite high, up to 4000 within 6 hours at low temperature atmospheric pressure. These kinds of complexes could be the promising materials for industrial chemistry to produce aromatic aldehydes or ketones.
author2	Tsun-Ren Chen
author_facet	Tsun-Ren Chen Pei-chun Liu 劉珮君
author	Pei-chun Liu 劉珮君
spellingShingle	Pei-chun Liu 劉珮君 Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
author_sort	Pei-chun Liu
title	Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
title_short	Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
title_full	Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
title_fullStr	Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
title_full_unstemmed	Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes
title_sort	synthesis, structure and catalytic character of cyclometalated iridium(iii) complexes
publishDate	2012
url	http://ndltd.ncl.edu.tw/handle/74803723769333787189
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Synthesis, Structure and Catalytic Character of Cyclometalated Iridium(III) Complexes

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