FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase

碩士 === 國立臺北科技大學 === 有機高分子研究所 === 100 === An efficient FeCl3•6H2O/cationic 2,2’-bipyridine system catalyzed cross-coupling of aryl iodides with activated olefins in water in the presence of Zn as the reductant, giving Michael-type addition products in good to high yields. The present system prov...

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Main Authors: Chun-Min Haung, 黃俊銘
Other Authors: Fu-Yu Tsai
Format: Others
Language:zh-TW
Published: 2012
Online Access:http://ndltd.ncl.edu.tw/handle/9766bk
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spelling ndltd-TW-100TIT053100752019-05-15T20:51:53Z http://ndltd.ncl.edu.tw/handle/9766bk FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase 以鐵三價在水中催化芳基碘與具有活性的烯類進行共軛加成 Chun-Min Haung 黃俊銘 碩士 國立臺北科技大學 有機高分子研究所 100 An efficient FeCl3•6H2O/cationic 2,2’-bipyridine system catalyzed cross-coupling of aryl iodides with activated olefins in water in the presence of Zn as the reductant, giving Michael-type addition products in good to high yields. The present system provides an extremely suitable catalyst for the activation of a variety of aryl iodides and it has two advantages: iron is the cheapest transition-metal, less environmental pollution and the greenest solvent, water, is employed as the reaction medium. Fu-Yu Tsai 蔡福裕 2012 學位論文 ; thesis 111 zh-TW
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language zh-TW
format Others
sources NDLTD
description 碩士 === 國立臺北科技大學 === 有機高分子研究所 === 100 === An efficient FeCl3•6H2O/cationic 2,2’-bipyridine system catalyzed cross-coupling of aryl iodides with activated olefins in water in the presence of Zn as the reductant, giving Michael-type addition products in good to high yields. The present system provides an extremely suitable catalyst for the activation of a variety of aryl iodides and it has two advantages: iron is the cheapest transition-metal, less environmental pollution and the greenest solvent, water, is employed as the reaction medium.
author2 Fu-Yu Tsai
author_facet Fu-Yu Tsai
Chun-Min Haung
黃俊銘
author Chun-Min Haung
黃俊銘
spellingShingle Chun-Min Haung
黃俊銘
FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
author_sort Chun-Min Haung
title FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
title_short FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
title_full FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
title_fullStr FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
title_full_unstemmed FeCl3-Catalyzed Conjugate Addition of Aryl Iodides with Activated Olefins in Aqueous Phase
title_sort fecl3-catalyzed conjugate addition of aryl iodides with activated olefins in aqueous phase
publishDate 2012
url http://ndltd.ncl.edu.tw/handle/9766bk
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