Study on the Diels-Alder Reactions of Masked o-Benzoquinoneswith 6,6-Dimethylfulvene
碩士 === 中原大學 === 化學研究所 === 101 === The thesis concerns with the intermolecular Diels-Alder reactions of masked o-benzoquinones (MOBs) with 6,6-Dimethylfulvene. Masked o-benzoquinones (MOBs) 2a-e generated in situ from 2-methoxyphenols 1a-e underwent intermolecular Diels-Alder reactions with a diene,...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2013
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| Online Access: | http://ndltd.ncl.edu.tw/handle/31926163509838645546 |
| Summary: | 碩士 === 中原大學 === 化學研究所 === 101 === The thesis concerns with the intermolecular Diels-Alder reactions of masked o-benzoquinones (MOBs) with 6,6-Dimethylfulvene. Masked o-benzoquinones (MOBs) 2a-e generated in situ from 2-methoxyphenols 1a-e underwent intermolecular Diels-Alder reactions with a diene, 6,6-dimethylfulvene to give cycloadducts, tricycle[5.2.2.02,6] undecaenones 3a-e, which were formed from the reactions that MOBs serve as diene and 6,6-dimethylfulvene as a dienophile.
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