Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands

碩士 === 國立中山大學 === 化學系研究所 === 101 === A series of new pyrazole-containing chiral oxazoline bidentate ligands have been designed, successfully synthesized, and applied to Asymmetric Henry Reaction. Pyrazole-containing chiral oxazoline bidentate ligand has been investigated in catalytic asymmetric Henr...

Full description

Bibliographic Details
Main Authors:	Yi-Ting Wei, 魏翊庭
Other Authors:	Ming-Jung Wu
Format:	Others
Language:	zh-TW
Published:	2013
Online Access:	http://ndltd.ncl.edu.tw/handle/92384492421436418861

id	ndltd-TW-101NSYS5065066
record_format	oai_dc
spelling	ndltd-TW-101NSYS50650662016-08-26T04:12:12Z http://ndltd.ncl.edu.tw/handle/92384492421436418861 Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands 吡類手性噁唑啉雙螯基配體銅催化不對稱亨利反應之研究 Yi-Ting Wei 魏翊庭碩士國立中山大學化學系研究所 101 A series of new pyrazole-containing chiral oxazoline bidentate ligands have been designed, successfully synthesized, and applied to Asymmetric Henry Reaction. Pyrazole-containing chiral oxazoline bidentate ligand has been investigated in catalytic asymmetric Henry reaction of nitroaldol compound with different Lewis acids.The Cu(OTf)2 complex furnished R enantiomer (yield 97%, 37% ee), and Cu(OAc)2 complex afforded S enantiomer (yield 82%, 17% ee). Ming-Jung Wu 吳明忠 2013 學位論文 ; thesis 144 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立中山大學 === 化學系研究所 === 101 === A series of new pyrazole-containing chiral oxazoline bidentate ligands have been designed, successfully synthesized, and applied to Asymmetric Henry Reaction. Pyrazole-containing chiral oxazoline bidentate ligand has been investigated in catalytic asymmetric Henry reaction of nitroaldol compound with different Lewis acids.The Cu(OTf)2 complex furnished R enantiomer (yield 97%, 37% ee), and Cu(OAc)2 complex afforded S enantiomer (yield 82%, 17% ee).
author2	Ming-Jung Wu
author_facet	Ming-Jung Wu Yi-Ting Wei 魏翊庭
author	Yi-Ting Wei 魏翊庭
spellingShingle	Yi-Ting Wei 魏翊庭 Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
author_sort	Yi-Ting Wei
title	Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
title_short	Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
title_full	Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
title_fullStr	Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
title_full_unstemmed	Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands
title_sort	asymmetric henry reaction catalyzed by copper complexes of pyrazole-containing chiral oxazoline bidentate ligands
publishDate	2013
url	http://ndltd.ncl.edu.tw/handle/92384492421436418861
work_keys_str_mv	AT yitingwei asymmetrichenryreactioncatalyzedbycoppercomplexesofpyrazolecontainingchiraloxazolinebidentateligands AT wèiyìtíng asymmetrichenryreactioncatalyzedbycoppercomplexesofpyrazolecontainingchiraloxazolinebidentateligands AT yitingwei bǐlèishǒuxìngězuòlínshuāngáojīpèitǐtóngcuīhuàbùduìchēnghēnglìfǎnyīngzhīyánjiū AT wèiyìtíng bǐlèishǒuxìngězuòlínshuāngáojīpèitǐtóngcuīhuàbùduìchēnghēnglìfǎnyīngzhīyánjiū
_version_	1718379874002927616

Asymmetric Henry Reaction Catalyzed by Copper Complexes of Pyrazole-containing Chiral Oxazoline Bidentate Ligands

Similar Items