| Summary: | 碩士 === 中原大學 === 化學研究所 === 102 === This thesis discusses the synthese, structures and properties of nine new coordination polymers containing dipyridyl amide and polycarboxylate ligands, including {[Cd(1,2-BDC)(L1)(H2O)]•H2O}n [L1 = N,N¢-di(3-pyridyl)suberoamide; 1,2-H2BDC = benzene-1,2-dicarboxylic Acid], 1; {[Cd2(1,3-BDC)2(L1)3]•8H2O}n (1,3-H2BDC = benzene-1,3-dicarboxylic Acid), 2; {[Cd0.5(1,4-BDC)0.5(L1)0.5(H2O)]}n (1,4-H2BDC = benzene-1,4-dicarboxylic Acid), 3; {[Cd(1,3-BDC)(L1)]•H2O}n, 4; [Cd(5-OH-IPA)(L1)]n (5-OH-IPA = 5-hydroxyisophthalic Acid), 5; {[Cd3(BTC)2(L1)3(H2O)3]•8H2O}n (1,3,5-H3BTC = 1,3,5-benzenetricarboxylic Acid), 6; [Co(5-OH-IPA)(L1)]n, 7; [Cd(5-Br-IPA)(L2)]n [L2 = N,N¢-di(4-pyridyl)suberoamide; 5-Br-H2IPA = 5-bromoisophthalic Acid], 8; [Cd(5-tert-IPA)(L2)0.5]n (5-tert-H2IPA = 5-tert-butylisophthalic Acid), 9. All the complexes have been characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analyses, thermogravimetric analyses, infrared spectrometer and fluorescence spectrometer. Complex 1 forms a loop-like 1D chain. Complex 2 forms a 3D framework with a new (65.8) topology. Complex 3 forms a 2D layer with a sql topology. Complexes 4, 5, and 7 show 2D double layers with a 3,5L2 topology. Complex 6 forms a 3D framework with a 3,4,4T90 topology. Complex 8 forms a two-fold interpenetrated 2D layer with a 2,6L1 topology. Complex 9 forms a 3D framework with a {510.63.7.8}{54.62} topology.
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