Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes
碩士 === 中原大學 === 化學研究所 === 102 === In this study, heterobimetallic palladium-cobalt tetraacetate was used as the catalyst for intermolecular aziridination and amination reactions. 2,2,2-trichloroethanol synthesis of 2,2,2-Trichloroethyl sulfamate was used as the source of nitrene, and PdCo(OAc)4 as t...
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ndltd-TW-102CYCU50650752016-03-11T04:13:46Z http://ndltd.ncl.edu.tw/handle/71294505569532642678 Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes 異核鈀鈷雙金屬錯合物催化烯類分子間氮丙啶化與胺化反應之研究 Chao-Chun Hung 洪肇駿 碩士 中原大學 化學研究所 102 In this study, heterobimetallic palladium-cobalt tetraacetate was used as the catalyst for intermolecular aziridination and amination reactions. 2,2,2-trichloroethanol synthesis of 2,2,2-Trichloroethyl sulfamate was used as the source of nitrene, and PdCo(OAc)4 as the catalyst to react with alkenes. And the products were aziridine and amine compound. PdCo(esp)2 as analog of PdCo(OAc)4, was synthesized and with a common catalyst for the comparison with palladium acetate, rhodium acetate, Rh2(esp)2 in their catalytic ability in nitrene insertion reaction. Gary Jing Chuang 莊 敬 2014 學位論文 ; thesis 107 zh-TW |
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碩士 === 中原大學 === 化學研究所 === 102 === In this study, heterobimetallic palladium-cobalt tetraacetate was used as the catalyst for intermolecular aziridination and amination reactions. 2,2,2-trichloroethanol synthesis of 2,2,2-Trichloroethyl sulfamate was used as the source of nitrene, and PdCo(OAc)4 as the catalyst to react with alkenes. And the products were aziridine and amine compound. PdCo(esp)2 as analog of PdCo(OAc)4, was synthesized and with a common catalyst for the comparison with palladium acetate, rhodium acetate, Rh2(esp)2 in their catalytic ability in nitrene insertion reaction.
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Gary Jing Chuang |
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Gary Jing Chuang Chao-Chun Hung 洪肇駿 |
author |
Chao-Chun Hung 洪肇駿 |
spellingShingle |
Chao-Chun Hung 洪肇駿 Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
author_sort |
Chao-Chun Hung |
title |
Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
title_short |
Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
title_full |
Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
title_fullStr |
Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
title_full_unstemmed |
Heterobimetallic Palladium-Cobalt Complex Catalyzed Intermolecular Aziridination and Amination of Alkenes |
title_sort |
heterobimetallic palladium-cobalt complex catalyzed intermolecular aziridination and amination of alkenes |
publishDate |
2014 |
url |
http://ndltd.ncl.edu.tw/handle/71294505569532642678 |
work_keys_str_mv |
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