含十六族元素 (硫、硒、碲) 之過度金屬 (鉻、錳、釕) 團簇化合物的合成、轉換關係、化性與物性研究
碩士 === 國立臺灣師範大學 === 化學系 === 102 === Te−Mn−CO system The reactions of Te powder, Mn2(CO)10, and quaternary ammonium salts (Et4NBr or TMBACl) in appropriate ratios in refluxing 1 M or 2 M KOH/MeOH/MeCN solutions led to the formation of the dumbbell-like paramagnetic complex [Te10Mn6(CO)18]4− (1) with...
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Format: | Others |
Language: | zh-TW |
Published: |
2014
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Online Access: | http://ndltd.ncl.edu.tw/handle/55313925410574366959 |