Studies on Syntheses of Indole Alkaloids using Rh-catalyzed Hydroformylation Domino Bicyclizations
碩士 === 國立中興大學 === 化學系所 === 103 === The thesis describes the investigation of nitrogen-nucleophile mediated Rh-catalyzed domino hydroformylation bicyclization reaction, which have been developed two ways to form tetracycle skeleton for application in the Chaetominine synthesis. The first way is con...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2015
|
| Online Access: | http://ndltd.ncl.edu.tw/handle/87073286056057590206 |
| Summary: | 碩士 === 國立中興大學 === 化學系所 === 103 === The thesis describes the investigation of nitrogen-nucleophile mediated Rh-catalyzed domino hydroformylation bicyclization reaction, which have been developed two ways to form tetracycle skeleton for application in the Chaetominine synthesis. The first way is construction of tricycle skeletons pyrroloindoline 43a and 43b, and tries to construct fourth ring. The other method is attempt to construct tricycle skeleton 13 and following fourth ring species 7 using 47 and 53.
|
|---|