Study of gold-catalyzed arylsulfonation of alkynes

碩士 === 國立交通大學 === 應用化學系碩博士班 === 103 === In this thesis, we investigated the catalyzed addition between sulfonic acid and enynes and diynes resulting vinyl sulfonates compounds by using AuCl(PPh3) as catalyst. In this content, we also optimized the reaction conditions and discussed the reactivity of...

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Bibliographic Details
Main Authors: Chen, Po-Yen, 陳柏言
Other Authors: Chuang, Shih-Ching
Format: Others
Language:zh-TW
Published: 2015
Online Access:http://ndltd.ncl.edu.tw/handle/z67f6q
Description
Summary:碩士 === 國立交通大學 === 應用化學系碩博士班 === 103 === In this thesis, we investigated the catalyzed addition between sulfonic acid and enynes and diynes resulting vinyl sulfonates compounds by using AuCl(PPh3) as catalyst. In this content, we also optimized the reaction conditions and discussed the reactivity of different functional groups as starting material. To characterize these vinyl sulfonates derivatives, we took advantage of NMR, IR, MS and X-ray diffraction.