Study on the synthesis and properties of poly(acrylic acid-co-acrylamide)/fly ash composite hydrogel

• Main Authors: Lan, Han-Zhong, 藍漢中
• Other Authors: Hsu, Kung-Chung
• Format: Others
• Language: zh-TW
• Published: 2015
• Online Access: http://ndltd.ncl.edu.tw/handle/39301253943970347119

碩士 === 國立臺灣師範大學 === 化學系 === 103 === This main goal of thesis is to prepare two anionic superabsorbent hydrogel, polyacrylic acid / polyacryl amide ( P(AA/AM) ) and polyacrylic acid / polyacryl amide / fly ash ( P(AA/AM)/FA ). Ammmonium persulfate ( APS) and N,N’methylene bisacrylamide (MBA) were used as an initiator and crosslinking agent, respectively. Using FT-IR to identify structure, surface porosity is observed by SEM. The parameters what could be effected experiment are monomer ratio, initiator dosage, crosslinker dosage, reaction temperature and proportion of fly ash. We measure water absorbency of hydrogel in water, saline solution and variety of different situation and then test the mechanical properties, including compressive strength and water absorption under load (AUL). We evaluate if P(AA/AM)/FA hydrogel whose additive quantity, proportion of fly ash and particle size is reasonablely applied to the grout and cement mortar as a self-curing agent. Then we researched hydration degree, cracking index, and setting time in grout. We calculated weight-loss, water retention,compressive strength, internal humidity, and drying shrinkage in cement mortar. The result indicate that P(AA/AM)/FA hydrogel in the optimum reaction condition, the water absorbency is 386 g/g in water, and 56, 26 g/g in 0.1M NaCl(aq) and 0.1M CaCl2(aq), repectively. The compressive strength is 47.5 (Kgf / cm2). When we add P(AA/AM)/FA hydrogel into mortar as self-curing reagent, the optimum dosage, particle size and proportion of fly ash is 0.2 wt%, 0.082 mm and 10 wt%, respectively, in this condition, improve the performance of weight-loss, compressive strength, internal humidity, drying shrinkage and craking formation. All the performance is better than the control group without P(AA/AM)/FA hydrogel.