1. Synthesis of Ni complexes and its ALD application 2. Design and synthesis of non-conjugate dipolar dihytroindenoindene derivatives

• Main Authors: Yi-Mei Huang, 黃怡梅
• Other Authors: Jen-Chieh Hsieh
• Format: Others
• Language: zh-TW
• Published: 2015
• Online Access: http://ndltd.ncl.edu.tw/handle/98955767655818899210

碩士 === 淡江大學 === 化學學系碩士班 === 103 === Part I: Atomic layer deposition method (ALD) deposited film have good thickness coverage rate and uniformity. With Ni(dmap)2 synthesis as discussed in comparative Ni(dmamb)2 and Ni(dmap)2 difference properties of the ligand. And we sent the Ni(dmap)2 precursor to do atomic deposition method, at several various conditions processes improved, we can observed densely Ni crystal island on the substrate. We research the substrate parameter adjustment let the film deposited more ideal. Part II: In this research we use 2,2''-(indeno[2,1-a]indene-5,10-diylidene)dimalononitrile and N,N-diphenylfuran-2-amine to do 4+2 reaction synthesized non-conjugated bridging three-dimensional structure, we hoped this non-conjugated characteristic after light effect excited exciton have charge separation, through this phenomena can be increase efficiency of solar cells.