Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells
博士 === 國立成功大學 === 化學工程學系 === 104 === This dissertation focuses on two aspects including the active layer/cathode interface for polymer light-emitting diodes (PLEDs) and polymer solar cells (PSCs) (Chapter 2-4) as well as the electron donor/acceptor interface in the bulk heterojunction (BHJ) for nonf...
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ndltd-TW-104NCKU50630142017-09-24T04:40:41Z http://ndltd.ncl.edu.tw/handle/85955992517452326072 Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells 界面工程於高效率高分子發光二極體與太陽能電池 Chen-HaoWu 吳振豪 博士 國立成功大學 化學工程學系 104 This dissertation focuses on two aspects including the active layer/cathode interface for polymer light-emitting diodes (PLEDs) and polymer solar cells (PSCs) (Chapter 2-4) as well as the electron donor/acceptor interface in the bulk heterojunction (BHJ) for nonfullerene PSCs (Chapter 5). In Chapter 2, an efficient PLED is demonstrated using octadecanamide (ODAD) as a solution-processed electron injection layer (EIL). The device with an ODAD/Al cathode exhibits the higher luminance efficiency (8.5 cd A-1) than that with a Ca/Al cathode (5.9 cd A-1). The ability for the EIL of ODAD to lower the electron injection barrier is investigated by the analysis of structural analogs, photovoltaic measurements, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy. The results verify the mechanism: the amide functional group forms the C-O-Al complex at the ODAD/Al interface to create the interfacial dipole for decreasing the work function (WF) of Al. In Chapter 3, tetra-n-alkyl ammonium bromides (TAABs) are demonstrated as solution-processed electron extraction layers (EELs) in BHJ PSCs based on poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM). The EELs of TAABs lead to simultaneous increases in open-circuit voltage (VOC), short-circuit current density, and fill factor, enhancing the power conversion efficiency (PCE) of BHJ PSCs from 2.38% to 4.02-4.19%. Interestingly, the constant increase in VOC of ≈0.14 V is obtained for devices with Al, Ag, and Au cathodes by using the EEL of tetraoctylammonium bromide (TOAB). The self-assembly of TOAB into the lamellar structure stacked upright atop P3HT:PCBM is corroborated by synchrotron X-ray diffraction (XRD). The underlying mechanism is inferred that the TAAB molecules introduce anisotropic dipoles toward P3HT:PCBM which decrease the WF of metals for the efficient electron extraction. In Chapter 4, TOAB is employed as a model compound to investigate the significance of ions with an ordered arrangement for enhancing the electron injection in PLEDs and the electron extraction in PSCs. The spin-coated films of TOAB are prepared on the active layers of both PLEDs and PSCs with the different thermal annealing processes. Subsequently, they are investigated by atomic force microscopy (AFM) and synchrotron XRD as well as simultaneously employed as the EIL or the EEL. The results reveal that the ordered arrangement of ions in the TOAB crystals is essential to enhance electron injection/extraction. In Chapter 5, it is shown how the molecular geometry of the polymer donors and the perylene diimide dimers (di-PDIs) influences the BHJ morphology in the nonfullerene PSCs. The results reveal that the pseudo 2D conjugated poly[4,8-bis(5-(2-ethylhexyl)thiophen-2- yl)benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)] (PTB7-Th) has better miscibility with both bay-linked di-PDI (B-di-PDI) and hydrazine-linked di-PDI (H-di-PDI) compared to its 1D analog, poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7), to facilitate more efficient exciton dissociation in the BHJ films. However, the face-on oriented π-π stacking of PTB7-Th is severely disrupted by the B-di-PDI due to its more flexible structure. On the contrary, the face-on oriented π-π stacking is only slightly disrupted by the H-di-PDI, which has a more rigid structure to provide suitable percolation pathways for charge transport. As a result, a very high PCE of 6.41% is achieved in the PTB7-Th:H-di-PDI derived device. Ten-Chin Wen 溫添進 2016 學位論文 ; thesis 92 en_US |
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博士 === 國立成功大學 === 化學工程學系 === 104 === This dissertation focuses on two aspects including the active layer/cathode interface for polymer light-emitting diodes (PLEDs) and polymer solar cells (PSCs) (Chapter 2-4) as well as the electron donor/acceptor interface in the bulk heterojunction (BHJ) for nonfullerene PSCs (Chapter 5).
In Chapter 2, an efficient PLED is demonstrated using octadecanamide (ODAD) as a solution-processed electron injection layer (EIL). The device with an ODAD/Al cathode exhibits the higher luminance efficiency (8.5 cd A-1) than that with a Ca/Al cathode (5.9 cd A-1). The ability for the EIL of ODAD to lower the electron injection barrier is investigated by the analysis of structural analogs, photovoltaic measurements, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy. The results verify the mechanism: the amide functional group forms the C-O-Al complex at the ODAD/Al interface to create the interfacial dipole for decreasing the work function (WF) of Al.
In Chapter 3, tetra-n-alkyl ammonium bromides (TAABs) are demonstrated as solution-processed electron extraction layers (EELs) in BHJ PSCs based on poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM). The EELs of TAABs lead to simultaneous increases in open-circuit voltage (VOC), short-circuit current density, and fill factor, enhancing the power conversion efficiency (PCE) of BHJ PSCs from 2.38% to 4.02-4.19%. Interestingly, the constant increase in VOC of ≈0.14 V is obtained for devices with Al, Ag, and Au cathodes by using the EEL of tetraoctylammonium bromide (TOAB). The self-assembly of TOAB into the lamellar structure stacked upright atop P3HT:PCBM is corroborated by synchrotron X-ray diffraction (XRD). The underlying mechanism is inferred that the TAAB molecules introduce anisotropic dipoles toward P3HT:PCBM which decrease the WF of metals for the efficient electron extraction.
In Chapter 4, TOAB is employed as a model compound to investigate the significance of ions with an ordered arrangement for enhancing the electron injection in PLEDs and the electron extraction in PSCs. The spin-coated films of TOAB are prepared on the active layers of both PLEDs and PSCs with the different thermal annealing processes. Subsequently, they are investigated by atomic force microscopy (AFM) and synchrotron XRD as well as simultaneously employed as the EIL or the EEL. The results reveal that the ordered arrangement of ions in the TOAB crystals is essential to enhance electron injection/extraction.
In Chapter 5, it is shown how the molecular geometry of the polymer donors and the perylene diimide dimers (di-PDIs) influences the BHJ morphology in the nonfullerene PSCs. The results reveal that the pseudo 2D conjugated poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-
yl)benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)] (PTB7-Th) has better miscibility with both bay-linked di-PDI (B-di-PDI) and hydrazine-linked di-PDI (H-di-PDI) compared to its 1D analog, poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7), to facilitate more efficient exciton dissociation in the BHJ films. However, the face-on oriented π-π stacking of PTB7-Th is severely disrupted by the B-di-PDI due to its more flexible structure. On the contrary, the face-on oriented π-π stacking is only slightly disrupted by the H-di-PDI, which has a more rigid structure to provide suitable percolation pathways for charge transport. As a result, a very high PCE of 6.41% is achieved in the PTB7-Th:H-di-PDI derived device.
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author2 |
Ten-Chin Wen |
author_facet |
Ten-Chin Wen Chen-HaoWu 吳振豪 |
author |
Chen-HaoWu 吳振豪 |
spellingShingle |
Chen-HaoWu 吳振豪 Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
author_sort |
Chen-HaoWu |
title |
Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
title_short |
Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
title_full |
Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
title_fullStr |
Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
title_full_unstemmed |
Interface Engineering toward Highly Efficient Polymer Light-Emitting Diodes and Solar Cells |
title_sort |
interface engineering toward highly efficient polymer light-emitting diodes and solar cells |
publishDate |
2016 |
url |
http://ndltd.ncl.edu.tw/handle/85955992517452326072 |
work_keys_str_mv |
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