Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers
碩士 === 國立交通大學 === 材料科學與工程學系奈米科技碩博士班 === 104 === We designed three carboxylic acid monomers A*B, A*FB and A*FBB containing acrylate group, and three different H-acceptors with pyridyl moiety. Due to the supramolecular forces between the H-donors and H-acceptors, a series of novel asymmetric hydrogen-...
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ndltd-TW-104NCTU51590022019-05-15T22:33:38Z http://ndltd.ncl.edu.tw/handle/5uy94r Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers 側鏈型雙桿狀氫鍵藍相液晶高分子之合成及其研究 Lin,Ray 林叡 碩士 國立交通大學 材料科學與工程學系奈米科技碩博士班 104 We designed three carboxylic acid monomers A*B, A*FB and A*FBB containing acrylate group, and three different H-acceptors with pyridyl moiety. Due to the supramolecular forces between the H-donors and H-acceptors, a series of novel asymmetric hydrogen-bonded dimeric complexes were self-assembled successfully. In addition, a series of Bi-Mesogenic Side-Chain Polymers were prepared by photo-polymerization. The result demonstrates that the combination of homopolymer pA*FB and the H-acceptor Py6CB, which have no chiral center on the alkyl chain, could induce the blue phase BP III. The temperature range of the pA*FB/Py6CB system is 8.2 oC. To further improve the blue phase polymer system, we have taken two ways. One way is that we used the copolymerization of A*B and A*FB to get the system p(A*FB+A*B)/Py6CB. The other is mixing two H-acceptors Py6CB and Py6*CB to increase the overall chirality of the polymer system. The former is fail to broaden the temperature range of BP, but the pA*FB/(Py6CB+Py6*CB) system can increase the temperature range to 10.4 oC when the ratio of Py6CB to Py6*CB is 9:1. Lin,Hong-Cheu 林宏洲 2015 學位論文 ; thesis 88 zh-TW |
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碩士 === 國立交通大學 === 材料科學與工程學系奈米科技碩博士班 === 104 === We designed three carboxylic acid monomers A*B, A*FB and A*FBB containing acrylate group, and three different H-acceptors with pyridyl moiety. Due to the supramolecular forces between the H-donors and H-acceptors, a series of novel asymmetric hydrogen-bonded dimeric complexes were self-assembled successfully.
In addition, a series of Bi-Mesogenic Side-Chain Polymers were prepared by photo-polymerization. The result demonstrates that the combination of homopolymer pA*FB and the H-acceptor Py6CB, which have no chiral center on the alkyl chain, could induce the blue phase BP III. The temperature range of the pA*FB/Py6CB system is 8.2 oC.
To further improve the blue phase polymer system, we have taken two ways. One way is that we used the copolymerization of A*B and A*FB to get the system p(A*FB+A*B)/Py6CB. The other is mixing two H-acceptors Py6CB and Py6*CB to increase the overall chirality of the polymer system. The former is fail to broaden the temperature range of BP, but the pA*FB/(Py6CB+Py6*CB) system can increase the temperature range to 10.4 oC when the ratio of Py6CB to Py6*CB is 9:1.
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author2 |
Lin,Hong-Cheu |
author_facet |
Lin,Hong-Cheu Lin,Ray 林叡 |
author |
Lin,Ray 林叡 |
spellingShingle |
Lin,Ray 林叡 Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
author_sort |
Lin,Ray |
title |
Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
title_short |
Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
title_full |
Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
title_fullStr |
Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
title_full_unstemmed |
Synthesis and Study of Hydrogen-Bonded Blue Phase Liquid Crystal Bi-Mesogenic Side-Chain Polymers |
title_sort |
synthesis and study of hydrogen-bonded blue phase liquid crystal bi-mesogenic side-chain polymers |
publishDate |
2015 |
url |
http://ndltd.ncl.edu.tw/handle/5uy94r |
work_keys_str_mv |
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