Research toward the synthesis of Marasmane skeleton
碩士 === 中原大學 === 化學研究所 === 105 === This thesis concerns with the intermolecular Diels-Alder reaction of masked o-benzoquinones (MOBs) with cyclopentadiene to form bicyclo[2.2.2]octenone, and then under the irradiation of a broad band of UV light centerded at 306 nm in acetonitrile, the bicyclo[2.2.2]...
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
2017
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Online Access: | http://ndltd.ncl.edu.tw/handle/85898741128095928471 |
Summary: | 碩士 === 中原大學 === 化學研究所 === 105 === This thesis concerns with the intermolecular Diels-Alder reaction of masked o-benzoquinones (MOBs) with cyclopentadiene to form bicyclo[2.2.2]octenone, and then under the irradiation of a broad band of UV light centerded at 306 nm in acetonitrile, the bicyclo[2.2.2]octenone performed sequential Norrish Type I, decarbonylation and 1,3-shift rearrangement to construct Marasmane skeleton.
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