1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals
碩士 === 國立中興大學 === 化學系所 === 105 === In the first part of this thesis, we report an efficient palladium-catalyzed ortho-C-H arylation of acetophenone oxime Ethers with aryl pinacol boronic esters, leading to the biaryl derivatives in good yields. The sequential process of iridium-catalyzed C-H borylat...
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ndltd-TW-105NCHU50650092017-11-12T04:39:00Z http://ndltd.ncl.edu.tw/handle/97404562666650034342 1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals 1.鈀金屬催化苯乙酮肟醚鄰位碳-氫鍵活化反應的探討2.藍色發光二極體促進硫縮醛合成之研究 Shao-Chien Wang 王韶謙 碩士 國立中興大學 化學系所 105 In the first part of this thesis, we report an efficient palladium-catalyzed ortho-C-H arylation of acetophenone oxime Ethers with aryl pinacol boronic esters, leading to the biaryl derivatives in good yields. The sequential process of iridium-catalyzed C-H borylation and palladium-catalyzed ortho-C-H arylation makes the present protocol access functionalized biaryl arenes. In the second part of this thesis, we achieve a simple and elegant method for dithioacetalization of aldehyde using blue LEDs irradiation under photochemical reaction. The salient features of this method are broad substrate scope, good tolerance of electron donating and withdrawing group, and metal free and solvent free conditions. It is noteworthy that our present protocol is eco-friendly in nature and we will develop LEDs-promoted reaction in future green chemistry avenues. 李進發 2017 學位論文 ; thesis 213 zh-TW |
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碩士 === 國立中興大學 === 化學系所 === 105 === In the first part of this thesis, we report an efficient palladium-catalyzed ortho-C-H arylation of acetophenone oxime Ethers with aryl pinacol boronic esters, leading to the biaryl derivatives in good yields. The sequential process of iridium-catalyzed C-H borylation and palladium-catalyzed ortho-C-H arylation makes the present protocol access functionalized biaryl arenes.
In the second part of this thesis, we achieve a simple and elegant method for dithioacetalization of aldehyde using blue LEDs irradiation under photochemical reaction. The salient features of this method are broad substrate scope, good tolerance of electron donating and withdrawing group, and metal free and solvent free conditions. It is noteworthy that our present protocol is eco-friendly in nature and we will develop LEDs-promoted reaction in future green chemistry avenues.
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李進發 |
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李進發 Shao-Chien Wang 王韶謙 |
author |
Shao-Chien Wang 王韶謙 |
spellingShingle |
Shao-Chien Wang 王韶謙 1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
author_sort |
Shao-Chien Wang |
title |
1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
title_short |
1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
title_full |
1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
title_fullStr |
1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
title_full_unstemmed |
1.Palladium-Catalyzed ortho-C-H Bond Activation of Acetophenone Oxime Ethers2.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals |
title_sort |
1.palladium-catalyzed ortho-c-h bond activation of acetophenone oxime ethers2.investigation of blue leds promoted synthesis of dithioacetals |
publishDate |
2017 |
url |
http://ndltd.ncl.edu.tw/handle/97404562666650034342 |
work_keys_str_mv |
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