Discussion on the crystal structures, spectroscopies and magnetic properties of Hg(2-NCH2-p-C6H4CH3NCTPP)I、Co(2-NCH2-p-C6H4CH3-21-CH2-m-C6H4CH3NCTPP)X, (X：Cl、NCS)、Co(2-NCH2-p-C6H4CH3-21-CH2C6H5NCTPP)(NCS)

• Main Authors: Chun-Yeh Lin, 林君燁
• Other Authors: 陳志鴻
• Format: Others
• Language: zh-TW
• Published: 2017
• Online Access: http://ndltd.ncl.edu.tw/handle/35351703722640657003

碩士 === 國立中興大學 === 化學系所 === 105 === We use 4-Methylbenzyl bromide as 2-N substituted alkylation to react with N-confused porphyrin to afford 2-aza-2-(p-methylbenyl)-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin (2-NCH2-p-C6H4CH3NCTPPH) (2). After 2-N substituted alkylation, we use HgI2, CoCl2 ∙ 6H2O and Co(SCN)2 to react seperately with 2-NCH2-p-C6H4CH3NCTPPH (2) to get four NCP metal complexes, diamagnetic of Hg(2-NCH2-p-C6H4 CH3NCTPP)I (3)、paramagnetic of Co(2-NCH2-p-C6H4CH3-21-CH2-m- C6H4CH3NCTPP)X (4, 5) (X：Cl、NCS) and Co(2-NCH2-p-C6H4CH3-21- CH2C6H5NCTPP)(NCS) (6). Then we use X-ray Single-Crystal Diffractometer, NMR spectroscopy and EPR spectroscopy, etc., to determine the crystal structures and discuss their physical properties.