Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS).
碩士 === 國立中興大學 === 化學系所 === 105 === We used 4-Isopropylbenzyl bromide and Benzyl bromoacetate as the alkylation reagent to react with N-confused porphyrin (NCP) to afford 2- aza-2-[p-(isopropyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2-p-C6H4-isoC3H7NCTPPH (2)] and 2-aza-2-benzyloxy...
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ndltd-TW-105NCHU50650522017-11-12T04:39:01Z http://ndltd.ncl.edu.tw/handle/56103835907354616012 Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). 探討 對-溴甲基異丙基苯 及 溴乙酸苯甲酯 修飾碳氮異位紫質:汞、鈷金屬錯合物之晶體結構、磁性與光譜研究 Hsiang-Yin Lin 林香吟 碩士 國立中興大學 化學系所 105 We used 4-Isopropylbenzyl bromide and Benzyl bromoacetate as the alkylation reagent to react with N-confused porphyrin (NCP) to afford 2- aza-2-[p-(isopropyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2-p-C6H4-isoC3H7NCTPPH (2)] and 2-aza-2-benzyloxycarbonylmethyl-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2COOCH2C6H5NCTPPH (5)]. After 2-N substituted alkylation, we used HgI2, Hg(SCN)2, CoCl2•6H2O, Co(SCN)2 to separately react with 2-NCH2-p-C6H4-isoC3H7NCTPPH (2) and 2-NCH2COOCH2C6H5NCTPPH (5) to get the five NCP metal complexes, Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I (3) , Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl (4) , Hg(2-NCH2COOCH2C6H5NCTPPH)I (6) , Hg(2-NCH2COOCH2C6H5NCTPPH)Cl (7) and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS) (9). Applying X-ray single-crystal diffractometer, Nuclear magnetic resonance spectrometer, Electron paramagnetic resonance spectrometer, Superconducting quantum interference device magnetometer, UV-visible spectrophotometer, UV-visible-NIR spectrophotometer, Elemental analyzer, Mass spectrometer characterized and studied the crystal structures of NCP metal complexes and the physical chemistry property. Jyh-Horung Chen 陳志鴻 2017 學位論文 ; thesis 126 zh-TW |
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碩士 === 國立中興大學 === 化學系所 === 105 === We used 4-Isopropylbenzyl bromide and Benzyl bromoacetate as the alkylation reagent to react with N-confused porphyrin (NCP) to afford 2- aza-2-[p-(isopropyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2-p-C6H4-isoC3H7NCTPPH (2)] and 2-aza-2-benzyloxycarbonylmethyl-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2COOCH2C6H5NCTPPH (5)]. After 2-N substituted alkylation, we used HgI2, Hg(SCN)2, CoCl2•6H2O, Co(SCN)2 to separately react with 2-NCH2-p-C6H4-isoC3H7NCTPPH (2) and 2-NCH2COOCH2C6H5NCTPPH (5) to get the five NCP metal complexes, Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I (3) , Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl (4) , Hg(2-NCH2COOCH2C6H5NCTPPH)I (6) , Hg(2-NCH2COOCH2C6H5NCTPPH)Cl (7) and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS) (9).
Applying X-ray single-crystal diffractometer, Nuclear magnetic resonance spectrometer, Electron paramagnetic resonance spectrometer, Superconducting quantum interference device magnetometer, UV-visible spectrophotometer, UV-visible-NIR spectrophotometer, Elemental analyzer, Mass spectrometer characterized and studied the crystal structures of NCP metal complexes and the physical chemistry property.
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Jyh-Horung Chen |
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Jyh-Horung Chen Hsiang-Yin Lin 林香吟 |
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Hsiang-Yin Lin 林香吟 |
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Hsiang-Yin Lin 林香吟 Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
author_sort |
Hsiang-Yin Lin |
title |
Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
title_short |
Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
title_full |
Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
title_fullStr |
Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
title_full_unstemmed |
Synthesis and characterization of metal complexes:Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS). |
title_sort |
synthesis and characterization of metal complexes:hg(2-nch2-p-c6h4-isoc3h7nctpph)i, co(2-nch2-p-c6h4-isoc3h7-21-ch2-o-c6h4ch3-nctpp)cl, hg(2-nch2cooch2c6h5nctpph)i, hg(2-nch2cooch2c6h5nctpph)cl and co(2-nch2cooch3-21-cn-nctpp)(ncs). |
publishDate |
2017 |
url |
http://ndltd.ncl.edu.tw/handle/56103835907354616012 |
work_keys_str_mv |
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