Synthesis and characterization of metal complexes：Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS).

• Main Authors: Hsiang-Yin Lin, 林香吟
• Other Authors: Jyh-Horung Chen
• Format: Others
• Language: zh-TW
• Published: 2017
• Online Access: http://ndltd.ncl.edu.tw/handle/56103835907354616012

碩士 === 國立中興大學 === 化學系所 === 105 === We used 4-Isopropylbenzyl bromide and Benzyl bromoacetate as the alkylation reagent to react with N-confused porphyrin (NCP) to afford 2- aza-2-[p-(isopropyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2-p-C6H4-isoC3H7NCTPPH (2)] and 2-aza-2-benzyloxycarbonylmethyl-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin [2-NCH2COOCH2C6H5NCTPPH (5)]. After 2-N substituted alkylation, we used HgI2, Hg(SCN)2, CoCl2•6H2O, Co(SCN)2 to separately react with 2-NCH2-p-C6H4-isoC3H7NCTPPH (2) and 2-NCH2COOCH2C6H5NCTPPH (5) to get the five NCP metal complexes, Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I (3) , Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl (4) , Hg(2-NCH2COOCH2C6H5NCTPPH)I (6) , Hg(2-NCH2COOCH2C6H5NCTPPH)Cl (7) and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS) (9). Applying X-ray single-crystal diffractometer, Nuclear magnetic resonance spectrometer, Electron paramagnetic resonance spectrometer, Superconducting quantum interference device magnetometer, UV-visible spectrophotometer, UV-visible-NIR spectrophotometer, Elemental analyzer, Mass spectrometer characterized and studied the crystal structures of NCP metal complexes and the physical chemistry property.