Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template
碩士 === 國立成功大學 === 材料科學及工程學系 === 105 === Copper metal filling into heat-treated anodized aluminum oxide (AAO) nano-array holes was attempted by electrodeposition involving emulsified supercritical carbon dioxide (sc-CO2) fluid, in comparison with that performed using conventional process at ambient p...
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ndltd-TW-105NCKU51591042019-05-15T23:53:19Z http://ndltd.ncl.edu.tw/handle/9f9arb Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template 利用超臨界二氧化碳電鍍法於經熱處理之陽極氧化鋁模板進行奈米孔銅金屬沉積之研究 De-WeiLin 林德瑋 碩士 國立成功大學 材料科學及工程學系 105 Copper metal filling into heat-treated anodized aluminum oxide (AAO) nano-array holes was attempted by electrodeposition involving emulsified supercritical carbon dioxide (sc-CO2) fluid, in comparison with that performed using conventional process at ambient pressure. The AAO template was likely hydrophobic in nature after being heat treated at 860 oC/24h. It had a dimension of about 5 um in thickness with an average hole-size of 60 nm and an aspect ratio of 83. Copper electrodeposition was conducted at 50 oC and at a pressure of 10 Mpa in an electrolyte consisting of 40 vol% of sc-CO2 and 60 vol% of CuSO4 aqueous solution. Both constant potential (-0.4 VPt, -0.5 VPt, -0.6 VPt) and constant current density (-10 mA/cm2) conditions were applied for metal filling. After electrodeposition, the extent of metal filling was examined using a scanning electron microscope (SEM) , and a transmission electron microscope (TEM), both coupled with an energy dispersive spectrometer (EDS). When as-anodized AAO template was used, a higher filling efficiency (in terms of cross section area percentage) was found in sc-CO2 bath than in conventional bath. When heat-treated AAO template was used, copper filling into the high aspect ratio nano-holes could be successfully achieved by sc-CO2 electrodeposition, while it was not possible in conventional bath. The advantage of sc-CO2 electrodeposition over that of conventional process was mainly attributed to the change of hydrophobicity of AAO template induced by heat treatment. Wen-Ta Tsai 蔡文達 2017 學位論文 ; thesis 96 zh-TW |
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碩士 === 國立成功大學 === 材料科學及工程學系 === 105 === Copper metal filling into heat-treated anodized aluminum oxide (AAO) nano-array holes was attempted by electrodeposition involving emulsified supercritical carbon dioxide (sc-CO2) fluid, in comparison with that performed using conventional process at ambient pressure. The AAO template was likely hydrophobic in nature after being heat treated at 860 oC/24h. It had a dimension of about 5 um in thickness with an average hole-size of 60 nm and an aspect ratio of 83. Copper electrodeposition was conducted at 50 oC and at a pressure of 10 Mpa in an electrolyte consisting of 40 vol% of sc-CO2 and 60 vol% of CuSO4 aqueous solution. Both constant potential (-0.4 VPt, -0.5 VPt, -0.6 VPt) and constant current density (-10 mA/cm2) conditions were applied for metal filling. After electrodeposition, the extent of metal filling was examined using a scanning electron microscope (SEM) , and a transmission electron microscope (TEM), both coupled with an energy dispersive spectrometer (EDS). When as-anodized AAO template was used, a higher filling efficiency (in terms of cross section area percentage) was found in sc-CO2 bath than in conventional bath. When heat-treated AAO template was used, copper filling into the high aspect ratio nano-holes could be successfully achieved by sc-CO2 electrodeposition, while it was not possible in conventional bath. The advantage of sc-CO2 electrodeposition over that of conventional process was mainly attributed to the change of hydrophobicity of AAO template induced by heat treatment.
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Wen-Ta Tsai |
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Wen-Ta Tsai De-WeiLin 林德瑋 |
author |
De-WeiLin 林德瑋 |
spellingShingle |
De-WeiLin 林德瑋 Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
author_sort |
De-WeiLin |
title |
Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
title_short |
Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
title_full |
Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
title_fullStr |
Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
title_full_unstemmed |
Application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
title_sort |
application of supercritical carbon dioxide electrodeposition for copper filling into nano-holes in heat-treated anodic aluminum oxide template |
publishDate |
2017 |
url |
http://ndltd.ncl.edu.tw/handle/9f9arb |
work_keys_str_mv |
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