Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy
碩士 === 國立交通大學 === 電子物理系所 === 107 === Two-dimensional material gallium selenide (GaSe) films were grown on sapphire, gallium nitride and gallium arsenide substrates by molecular beam epitaxy. The optical properties of GaSe films were analyzed by the Raman spectroscopy. The Effects of growth condition...
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ndltd-TW-107NCTU54290472019-11-26T05:16:53Z http://ndltd.ncl.edu.tw/handle/pgzc76 Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy 以分子束磊晶成長二維層狀硒化鎵之結構與拉曼光譜分析 Yan, Li-Jhen 顏利甄 碩士 國立交通大學 電子物理系所 107 Two-dimensional material gallium selenide (GaSe) films were grown on sapphire, gallium nitride and gallium arsenide substrates by molecular beam epitaxy. The optical properties of GaSe films were analyzed by the Raman spectroscopy. The Effects of growth conditions, different substrate temperatures, Se/Ga flux ratio and epitaxial time, on the epitaxial morphology and Raman spectrum were studied. The pyramidal structure of GaSe indicates that its growth mechanism is layer-by-layer growth. A structure change, from pyramid to closed-loop triangular structure, with the increasing epitaxial time was observed. The closed-loop triangular structure is caused by the concentric multilayer growth, which accompanies a lift of the GaSe E_2g^1 mode degeneracy in the Raman spectrum. It implies the presence of in-plane stress, which results in the change of growth mechanism of GaSe. Chou, Wu-Ching 周武清 2019 學位論文 ; thesis 45 zh-TW |
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碩士 === 國立交通大學 === 電子物理系所 === 107 === Two-dimensional material gallium selenide (GaSe) films were grown on sapphire, gallium nitride and gallium arsenide substrates by molecular beam epitaxy. The optical properties of GaSe films were analyzed by the Raman spectroscopy. The Effects of growth conditions, different substrate temperatures, Se/Ga flux ratio and epitaxial time, on the epitaxial morphology and Raman spectrum were studied. The pyramidal structure of GaSe indicates that its growth mechanism is layer-by-layer growth. A structure change, from pyramid to closed-loop triangular structure, with the increasing epitaxial time was observed. The closed-loop triangular structure is caused by the concentric multilayer growth, which accompanies a lift of the GaSe E_2g^1 mode degeneracy in the Raman spectrum. It implies the presence of in-plane stress, which results in the change of growth mechanism of GaSe.
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Chou, Wu-Ching |
author_facet |
Chou, Wu-Ching Yan, Li-Jhen 顏利甄 |
author |
Yan, Li-Jhen 顏利甄 |
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Yan, Li-Jhen 顏利甄 Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
author_sort |
Yan, Li-Jhen |
title |
Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
title_short |
Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
title_full |
Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
title_fullStr |
Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
title_full_unstemmed |
Structure and Raman Spectra Analysis of 2D-Layered Gallium Selenide Grown by Molecular Beam Epitaxy |
title_sort |
structure and raman spectra analysis of 2d-layered gallium selenide grown by molecular beam epitaxy |
publishDate |
2019 |
url |
http://ndltd.ncl.edu.tw/handle/pgzc76 |
work_keys_str_mv |
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