Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures
博士 === 國立交通大學 === 應用化學系碩博士班 === 107 === When polymers are introduced into nanoporous templates, polymer nanomaterials can be obtained. Their structures at different scales, from chain alignments and phase-separated morphologies on a single nanostructure to the overall replicated nanostructure arrays...
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ndltd-TW-107NCTU55000612019-11-26T05:16:52Z http://ndltd.ncl.edu.tw/handle/z9ed29 Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures 陽極氧化鋁模板與高分子:嵌段共聚物之形貌控制及離子液體高分子奈米結構之特性探討 Cheng, Ming-Hsiang 鄭名翔 博士 國立交通大學 應用化學系碩博士班 107 When polymers are introduced into nanoporous templates, polymer nanomaterials can be obtained. Their structures at different scales, from chain alignments and phase-separated morphologies on a single nanostructure to the overall replicated nanostructure arrays, can be affected and controlled by the porous templates, polymers, infiltration approaches, and other parameters applied. In this thesis, we discuss the morphology control of polymers confined in cylindrical nanopores and the characterization of replicated polymer nanostructure arrays. For the morphology control of polymers, microphase-separated morphologies of block copolymers confined in cylindrical nanopores are mainly studied. By imposing several parameters, such as annealing solvents (Chapter 3) and homopolymer additives (Chapter 4), various morphologies of block copolymer nanostructures can be obtained. We then characterize the effects of these parameters on the morphologies of block copolymer nanostructures. In Chapter 5, morphologies of amphiphilic block copolymer micelles confined in cylindrical nanopores are controlled by the annealing solvents and the hybridization with inorganic percursors. For the characterization of nanostructure arrays (Chapter 6), ionic diodes with interfacial interdigitated nanostructures are prepared by sequentially polymerizing and crosslinking ionic liquid monomers in AAO nanopores. By increasing the interfacial areas of ionic diodes using the template method, the “ionic double layer” capacitance is subsequently increased, which is further demonstrated as a device for mechanical energy harvesting. To sum up, this thesis provides a deeper understanding to the morphology control of polymers on a single nanostructure (microphase-separated morphologies of block copolymers) and characterizations of replicated nanostructure arrays (ionic diodes with interfacial interdigitated nanostructures). Chen, Jiun-Tai 陳俊太 2019 學位論文 ; thesis 148 zh-TW |
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博士 === 國立交通大學 === 應用化學系碩博士班 === 107 === When polymers are introduced into nanoporous templates, polymer nanomaterials can be obtained. Their structures at different scales, from chain alignments and phase-separated morphologies on a single nanostructure to the overall replicated nanostructure arrays, can be affected and controlled by the porous templates, polymers, infiltration approaches, and other parameters applied.
In this thesis, we discuss the morphology control of polymers confined in cylindrical nanopores and the characterization of replicated polymer nanostructure arrays. For the morphology control of polymers, microphase-separated morphologies of block copolymers confined in cylindrical nanopores are mainly studied. By imposing several parameters, such as annealing solvents (Chapter 3) and homopolymer additives (Chapter 4), various morphologies of block copolymer nanostructures can be obtained. We then characterize the effects of these parameters on the morphologies of block copolymer nanostructures. In Chapter 5, morphologies of amphiphilic block copolymer micelles confined in cylindrical nanopores are controlled by the annealing solvents and the hybridization with inorganic percursors.
For the characterization of nanostructure arrays (Chapter 6), ionic diodes with interfacial interdigitated nanostructures are prepared by sequentially polymerizing and crosslinking ionic liquid monomers in AAO nanopores. By increasing the interfacial areas of ionic diodes using the template method, the “ionic double layer” capacitance is subsequently increased, which is further demonstrated as a device for mechanical energy harvesting.
To sum up, this thesis provides a deeper understanding to the morphology control of polymers on a single nanostructure (microphase-separated morphologies of block copolymers) and characterizations of replicated nanostructure arrays (ionic diodes with interfacial interdigitated nanostructures).
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author2 |
Chen, Jiun-Tai |
author_facet |
Chen, Jiun-Tai Cheng, Ming-Hsiang 鄭名翔 |
author |
Cheng, Ming-Hsiang 鄭名翔 |
spellingShingle |
Cheng, Ming-Hsiang 鄭名翔 Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
author_sort |
Cheng, Ming-Hsiang |
title |
Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
title_short |
Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
title_full |
Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
title_fullStr |
Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
title_full_unstemmed |
Anodic Aluminum Oxide Templates and Polymers: Morphology Control of Block Copolymers and Characterizations of Poly (Ionic Liquid) Nanostructures |
title_sort |
anodic aluminum oxide templates and polymers: morphology control of block copolymers and characterizations of poly (ionic liquid) nanostructures |
publishDate |
2019 |
url |
http://ndltd.ncl.edu.tw/handle/z9ed29 |
work_keys_str_mv |
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