Reaction of rhodium III chlorides with ethylene in aqueous HC1 solution.
In the presence of iron (III) and other oxidants, HCl solutions of RhCl₃.3H₂O under mild conditions catalyze the oxidation of ethylene to acetaldehyde. The kinetics of the reaction measured by gas-uptake techniques indicate the presence of both ethylene dependent and independent steps. Hydroxy speci...
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Language: | English |
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University of British Columbia
2011
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Online Access: | http://hdl.handle.net/2429/34499 |