Application of the oxo reaction to various carbohydrate derivatives
3,4,6-Tri-0-acetyl-D-glucal (1) reacted with carbon monoxide and hydrogen in the presence of dicobalt octacarbonyl to yield a mixture of two epimeric anhydrodeoxyheptitols, namely, 4,5,7-tri-0-acetyl-2,6-anhydro-3-deoxy-D-manno-heptitol (2) and 4,5,7-tri-0-acetyl-2,6-anhydro-3-deoxy-D-gluco-heptitol...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/38083 |