Biofilms on silicone rubber for outdoor high voltage insulation

• Main Author: Wallström, Stina
• Format: Doctoral Thesis
• Language: English
• Published: KTH, Fiber- och polymerteknik 2005
• Subjects: Chemical engineering; polymer technology; Kemiteknik
• Online Access: http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-171; http://nbn-resolving.de/urn:isbn:91-7283-999-6

Silicone rubber high voltage insulators are sometimes colonised by microorganisms which form a biofilm on the surface of the infected unit. In this work insulators exposed to the outdoor environment in Sweden, Sri Lanka and Tanzania respectively have been studied. The biofilms colonising the insulators were shown to be of roughly the same composition regardless of their origin. Algae in association with bacteria dominated the biofilms and provided nutrition to mold growth. The isolated microorganisms were further used to study the effect of a biofilm on different silicone rubber materials. New tools for diagnosing biological growth on polymeric materials were developed and used to analyse the silicone rubber samples. No evidence of biodegradation of the polydimethylsiloxane (PDMS) molecule has been found in this work. However, this does not mean that PDMS rubbers used in high voltage insulators can be called bioresistant. Silicone insulating materials always contain additives and these may promote or hinder growth. For this reason, an extensive test program was developed, in order to evaluate the effect of different additives on the degree of biological growth. The program spanned from fast and easy methods, useful for screening large amount of samples, to the construction of specially designed microenvironment chambers in which mixed biofilms, similar to those formed on the surface of silicone rubber insulators in the field, were successfully grown. The test program showed that the flame retardant zinc borate protected the materials, whereas alumina trihydrate (ATH) did not hinder biological growth. On the contrary, environmental scanning microscopy (ESEM) in combination with X-ray energy dispersive spectroscopy (EDS) showed that the surface roughening caused by the addition of ATH to the silicone rubber matrix made the materials more difficult to clean. Furthermore when the hydrophobic surface of a silicone rubber insulator is covered by a hydrophilic biofilm this leads to a reduction of the surface hydrophobicity of the material. This may alter the electrical properties of the insulator. It is therefore important to develop methods to identify biofouled units. In this work, laser-induced fluorescence (LIF) spectroscopy was explored as a tool for the detection of biofilms on silicone rubbers. The experiments revealed that weak traces of algae or fungal growth, even those not visible to the naked eye, could be detected by this technique. In addition, it was shown that photography and subsequent digital image analysis could be utilised to estimate the area covered by biofilm growth. The results obtained indicate that LIF spectroscopy in combination with image analysis could be used for field diagnostics of biological growth on insulators in service.