Oxidative additions of amides to an iridium(I) metal center
Carboxylic amides will add oxidatively via N-H activation to the complex [(COD)Ir(PMe3h]CI (where COD 1,5-cyclooctadiene) in organic solvents at 80°C to form stable iridium hydrides with the hydride arranged cis to nitrogen and trans to chloride. Acetamide will add to form the complex mer-(MeC(O)...
Main Author: | Clark, Robert D. |
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Other Authors: | Chemistry |
Format: | Others |
Language: | en |
Published: |
Virginia Tech
2014
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Subjects: | |
Online Access: | http://hdl.handle.net/10919/43458 http://scholar.lib.vt.edu/theses/available/etd-06232009-063527/ |
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