Photodynamics of single quantum dots
A range of photochemical processes in biologically compatible quantum dots (QDs) at the individual nanocrystal level has been examined. Using objective type total internal reflection fluorescence microscopy we demonstrate the observation of photoluminescence activation (PLA), enhancement (PLE), fluo...
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ndltd-bl.uk-oai-ethos.bl.uk-4949322015-03-20T04:22:18ZPhotodynamics of single quantum dotsLee, Steven Frank2009A range of photochemical processes in biologically compatible quantum dots (QDs) at the individual nanocrystal level has been examined. Using objective type total internal reflection fluorescence microscopy we demonstrate the observation of photoluminescence activation (PLA), enhancement (PLE), fluorescence intermittency (Fl), decay and spectral shifting over the photochemical lifetimes of single QDs. The ability to count individual QDs along with their intensities has revealed a measurable nonlinear correlation between the total fluorescence and the QD population that is the result of enhancement and decay in the quantum yield (QY) of individual dots. This allows the differentiation between ensemble photoluminescence enhancement due to the fluorescence activation of a dark, non-emitting fraction of QDs (PLA) and that due to genuine QY modification in individual nanocrystals (PLE).621.38152University of Sussexhttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.494932Electronic Thesis or Dissertation |
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621.38152 Lee, Steven Frank Photodynamics of single quantum dots |
description |
A range of photochemical processes in biologically compatible quantum dots (QDs) at the individual nanocrystal level has been examined. Using objective type total internal reflection fluorescence microscopy we demonstrate the observation of photoluminescence activation (PLA), enhancement (PLE), fluorescence intermittency (Fl), decay and spectral shifting over the photochemical lifetimes of single QDs. The ability to count individual QDs along with their intensities has revealed a measurable nonlinear correlation between the total fluorescence and the QD population that is the result of enhancement and decay in the quantum yield (QY) of individual dots. This allows the differentiation between ensemble photoluminescence enhancement due to the fluorescence activation of a dark, non-emitting fraction of QDs (PLA) and that due to genuine QY modification in individual nanocrystals (PLE). |
author |
Lee, Steven Frank |
author_facet |
Lee, Steven Frank |
author_sort |
Lee, Steven Frank |
title |
Photodynamics of single quantum dots |
title_short |
Photodynamics of single quantum dots |
title_full |
Photodynamics of single quantum dots |
title_fullStr |
Photodynamics of single quantum dots |
title_full_unstemmed |
Photodynamics of single quantum dots |
title_sort |
photodynamics of single quantum dots |
publisher |
University of Sussex |
publishDate |
2009 |
url |
http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.494932 |
work_keys_str_mv |
AT leestevenfrank photodynamicsofsinglequantumdots |
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1716784952487444480 |