A new cyclohexyl-based chiral auxiliary : application in the total synthesis of (+)-linalool oxide
Seven different racemic cyclohexyl-based chiral auxiliaries (2.4-2.10) were synthesised in moderate to good yields (38-85%) by nucleophilic opening of cyclohexene oxide using carbanions. The racemic cyclohexyl-based chiral auxiliaries were coupled with the 6-methyl-2- methylenehept-5-enoyl chloride...
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University of Southampton
2010
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.561500 |