Boron halides and their cyclic derivations
An infrared study has been undertaken to investigate the mode of association in 2-chloro-1,3,2-dioxaborolan. Comments upon this and the spectrum in general are included. The kinetics for the pyrolysis of the above compound were subjected to a semi-quantitative study, from which it was possible to co...
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Royal Holloway, University of London
1964
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.703916 |
| Summary: | An infrared study has been undertaken to investigate the mode of association in 2-chloro-1,3,2-dioxaborolan. Comments upon this and the spectrum in general are included. The kinetics for the pyrolysis of the above compound were subjected to a semi-quantitative study, from which it was possible to conclude that the reaction was energetically favourable but sterically hampered. Attempts were made to prepare cyclic diboron compounds but the results were inconclusive. The vibrational spectra of certain selected diboron compounds, boron halides and dimethylamine have been studied in detail. The assignment of fundamental modes and some combination bands has been attempted. |
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