Boron halides and their cyclic derivations

An infrared study has been undertaken to investigate the mode of association in 2-chloro-1,3,2-dioxaborolan. Comments upon this and the spectrum in general are included. The kinetics for the pyrolysis of the above compound were subjected to a semi-quantitative study, from which it was possible to co...

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Main Author: Hyams, Ivan Julian
Published: Royal Holloway, University of London 1964
Subjects:
546
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.703916
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spelling ndltd-bl.uk-oai-ethos.bl.uk-7039162018-06-12T03:46:58ZBoron halides and their cyclic derivationsHyams, Ivan Julian1964An infrared study has been undertaken to investigate the mode of association in 2-chloro-1,3,2-dioxaborolan. Comments upon this and the spectrum in general are included. The kinetics for the pyrolysis of the above compound were subjected to a semi-quantitative study, from which it was possible to conclude that the reaction was energetically favourable but sterically hampered. Attempts were made to prepare cyclic diboron compounds but the results were inconclusive. The vibrational spectra of certain selected diboron compounds, boron halides and dimethylamine have been studied in detail. The assignment of fundamental modes and some combination bands has been attempted.546Inorganic ChemistryRoyal Holloway, University of Londonhttp://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.703916http://repository.royalholloway.ac.uk/items/c4a28455-1e5d-4ef0-abea-bd40aff06f2e/1/Electronic Thesis or Dissertation
collection NDLTD
sources NDLTD
topic 546
Inorganic Chemistry
spellingShingle 546
Inorganic Chemistry
Hyams, Ivan Julian
Boron halides and their cyclic derivations
description An infrared study has been undertaken to investigate the mode of association in 2-chloro-1,3,2-dioxaborolan. Comments upon this and the spectrum in general are included. The kinetics for the pyrolysis of the above compound were subjected to a semi-quantitative study, from which it was possible to conclude that the reaction was energetically favourable but sterically hampered. Attempts were made to prepare cyclic diboron compounds but the results were inconclusive. The vibrational spectra of certain selected diboron compounds, boron halides and dimethylamine have been studied in detail. The assignment of fundamental modes and some combination bands has been attempted.
author Hyams, Ivan Julian
author_facet Hyams, Ivan Julian
author_sort Hyams, Ivan Julian
title Boron halides and their cyclic derivations
title_short Boron halides and their cyclic derivations
title_full Boron halides and their cyclic derivations
title_fullStr Boron halides and their cyclic derivations
title_full_unstemmed Boron halides and their cyclic derivations
title_sort boron halides and their cyclic derivations
publisher Royal Holloway, University of London
publishDate 1964
url http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.703916
work_keys_str_mv AT hyamsivanjulian boronhalidesandtheircyclicderivations
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