Restricted rotation in sterically hindered diarylamines : structural requirements, synthesis, and applications of a new class of atropisomers

Although the stereochemistry of most atropisomers arises from slow rotation about a C-C bond, the ability of the nitrogen atom to adopt a planar geometry promotes conformational rigidity in anilides and aryl ureas. Diarylamines are closely related in architecture to the conformationally stable diary...

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Bibliographic Details
Main Author: Costil, Romain
Other Authors: Butts, Craig ; Clayden, Jonathan
Published: University of Bristol 2019
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.767984

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