Synthesis and structures of lanthanide metal amides.

• Other Authors: Kui, Chi Fai.
• Format: Others
• Language: English; Chinese
• Published: 2001
• Subjects: Organorare earth metal compounds; Organic compounds > Synthesis; Rare earth metals; Amides
• Online Access: http://library.cuhk.edu.hk/record=b5890623; http://repository.lib.cuhk.edu.hk/en/item/cuhk-323445

by Kui Chi Fai. === Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. === Includes bibliographical references. === Abstracts in English and Chinese. === Acknowledgements --- p.i === Abstracts --- p.ii === Table of Contents --- p.v === Abbreviations --- p.viii === Chapter CHAPTER 1. --- METALLATION OF AMINOPYRIDINE AND AMINOQUINOLINE === Chapter 1.1 --- INTRODUCTION --- p.1 === Chapter 1.1.1 --- General Background --- p.1 === Chapter 1.1.2 --- A Brief Review on Sodium and Potassium Amides --- p.3 === Chapter 1.1.3 --- Preparation of Sodium and Potassium Amides --- p.8 === Chapter 1.2 --- RESULTS AND DISCUSSION --- p.10 === Chapter 1.2.1 --- "Synthesis of [NH(SiButMe2)(R)] [ R = 2-C5H3N-6-Me, 8-C9H6N ] as Ligand Precursors" --- p.10 === Chapter 1.2.2 --- Synthesis of Sodium and Potassium Amido Complexes Containing the Pyridine-Functionalized Amido Ligand [N(SiButMe2)(2-C5H3N-6-Me)]- --- p.11 === Chapter 1.2.2.1 --- Sodium Pyridyl Amido Complexes --- p.11 === Chapter 1.2.2.2 --- Potassium Pyridyl Amido Complexes --- p.12 === Chapter 1.2.3 --- Synthesis of Sodium and Potassium Amido Complexes Containing the Quinoline-Functionalized Amido Ligand [N(SiButMe2)(8-C9H6N)]- --- p.15 === Chapter 1.2.3.1 --- Sodium Quinolyl Amido Complexes --- p.15 === Chapter 1.2.3.2 --- Potassium Quinolyl Amido Complexes --- p.16 === Chapter 1.2.4 --- Physical Characterization of Compounds 3-9 --- p.17 === Chapter 1.2.5 --- "Molecular Structures of Compounds 3, 5 and 7" --- p.20 === Chapter 1.3 --- EXPERIMENTALS FOR CHAPTER 1 --- p.30 === Chapter 1.3 --- REFERENCES FOR CHAPTER 1 --- p.36 === Chapter CHAPTER 2. --- "Synthesis,Structures, and Catalytic Properties of Lanthanide Metal Amides Containing the Pyridine - Functionalized Amido Ligand [N(SiButMe2)(2-C5H3N-6-Me)]-" === Chapter 2.1 --- INTRODUCTION --- p.39 === Chapter 2.1.1 --- General Background --- p.39 === Chapter 2.1.2 --- A Brief Review on Rare Earth Amido Complexes --- p.40 === Chapter 2.1.3 --- General Preparation Methods to Lanthanide Metal Amides --- p.44 === Chapter 2.1.4 --- Ring-Opening Polymerization of Lactones --- p.45 === Chapter 2.1.5 --- Objectives of This Work --- p.48 === Chapter 2.2 --- RESULTS AND DISCUSSION --- p.49 === Chapter 2.2.1 --- Synthesis and Physical Properties --- p.49 === Chapter 2.2.1.1 --- Homoleptic Lanthanide Metal Amides 10-18 --- p.49 === Chapter 2.2.1.2 --- Heteroleptic Lanthanide Metal Amides 19-22 --- p.53 === Chapter 2.2.2 --- Molecular Structures --- p.56 === Chapter 2.2.2.1 --- Molecular Structures of Homoleptic Lanthanide Metal Amides 10-18 --- p.56 === Chapter 2.2.2.2 --- Molecular Structures of Heteroleptic Lanthanide Metal Amides 19-22..… --- p.76 === Chapter 2.2.3 --- Reactivity Studies --- p.89 === Chapter 2.2.3.1 --- "Reaction with 3,5-di-tert-butylcatechol (dbcH2)" --- p.89 === Chapter 2.2.3.2 --- Ring-Opening Polymerization of s-Caprolactone --- p.95 === Chapter 2.3 --- EXPERIMENTALS FOR CHAPTER 2 --- p.100 === Chapter 2.4 --- REFERENCES FOR CHAPTER 2 --- p.108 === Chapter CHAPTER 3. --- Preparation of Pyridine Adducts of Zinc(II) Chloride and Low-coordinate Zinc(II) Dithiolate and Bis(aryloxide) Compounds === Chapter 3.1 --- INTRODUCTION --- p.111 === Chapter 3.1.1 --- General Background --- p.111 === Chapter 3.2 --- RESULTS AND DISCUSSION --- p.115 === Chapter 3.2.1 --- Synthesis of Pyridine Adducts of Zinc(II) Chloride --- p.115 === Chapter 3.2.2 --- Synthesis of Novel Three-Coordinate Zinc(II) Dithiolate and Bis(aryloxide) --- p.116 === Chapter 3.2.3 --- Physical Characterization of Compounds 23-26 --- p.118 === Chapter 3.2.4 --- Molecular Structures of Compounds 23-25 --- p.122 === Chapter 3.3 --- EXPERIMENTALS FOR CHAPTER 3 --- p.129 === Chapter 3.4 --- REFERENCES FOR CHAPTER 3 --- p.133 === Chapter CHAPTER 4. --- Summary of this Research Work --- p.135 === Appendix 1 General Procedures and Physical Measurements --- p.137 === "Appendix 2 Table A-l. Selected Crystallographic Data for Compounds 3, 5，7，10 and 11" --- p.139 === Table A-2. Selected Crystallographic Data for Compounds12-16 --- p.140 === Table A-3. Selected Crystallographic Data for Compounds17-21 --- p.141 === Table A-4. Selected Crystallographic Data for Compounds22-25 --- p.142