The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
Includes bibliographical references. === The synthesis and characterization of a series of new osmium(ll)dibromido complexes of the type [(116-Ar)OsLBr2] (Ar = p-cymene and C6Me6, L = phosphines, phosphites and CO) have been carried out successfully. The complexes were obtained in good yields and ch...
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| Format: | Dissertation |
| Language: | English |
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University of Cape Town
2014
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| Online Access: | http://hdl.handle.net/11427/10668 |
| Summary: | Includes bibliographical references. === The synthesis and characterization of a series of new osmium(ll)dibromido complexes of the type [(116-Ar)OsLBr2] (Ar = p-cymene and C6Me6, L = phosphines, phosphites and CO) have been carried out successfully. The complexes were obtained in good yields and characterized by 1 Hand 31 P NMR spectroscopy and elemental analysis. The dibromido complexes were then used in the preparation of osmium bis(alkenyl) and osmacycloalkane complexes. |
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