The synthesis, characterization and reactivity of metallacycloalkanes and their precursors

Includes bibliographical references. === The synthesis and characterization of a series of new osmium(ll)dibromido complexes of the type [(116-Ar)OsLBr2] (Ar = p-cymene and C6Me6, L = phosphines, phosphites and CO) have been carried out successfully. The complexes were obtained in good yields and ch...

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Main Author:	Makhubela, Banothile Charity Events
Other Authors:	Moss, John R
Format:	Dissertation
Language:	English
Published:	University of Cape Town 2014
Online Access:	http://hdl.handle.net/11427/10668

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spelling	ndltd-netd.ac.za-oai-union.ndltd.org-uct-oai-localhost-11427-106682021-07-07T05:09:09Z The synthesis, characterization and reactivity of metallacycloalkanes and their precursors Makhubela, Banothile Charity Events Moss, John R Smith, Gregory S Includes bibliographical references. The synthesis and characterization of a series of new osmium(ll)dibromido complexes of the type [(116-Ar)OsLBr2] (Ar = p-cymene and C6Me6, L = phosphines, phosphites and CO) have been carried out successfully. The complexes were obtained in good yields and characterized by 1 Hand 31 P NMR spectroscopy and elemental analysis. The dibromido complexes were then used in the preparation of osmium bis(alkenyl) and osmacycloalkane complexes. 2014-12-30T19:57:23Z 2014-12-30T19:57:23Z 2008 Master Thesis Masters MSc http://hdl.handle.net/11427/10668 eng application/pdf University of Cape Town Faculty of Science Department of Chemistry
collection	NDLTD
language	English
format	Dissertation
sources	NDLTD
description	Includes bibliographical references. === The synthesis and characterization of a series of new osmium(ll)dibromido complexes of the type [(116-Ar)OsLBr2] (Ar = p-cymene and C6Me6, L = phosphines, phosphites and CO) have been carried out successfully. The complexes were obtained in good yields and characterized by 1 Hand 31 P NMR spectroscopy and elemental analysis. The dibromido complexes were then used in the preparation of osmium bis(alkenyl) and osmacycloalkane complexes.
author2	Moss, John R
author_facet	Moss, John R Makhubela, Banothile Charity Events
author	Makhubela, Banothile Charity Events
spellingShingle	Makhubela, Banothile Charity Events The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
author_sort	Makhubela, Banothile Charity Events
title	The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
title_short	The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
title_full	The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
title_fullStr	The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
title_full_unstemmed	The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
title_sort	synthesis, characterization and reactivity of metallacycloalkanes and their precursors
publisher	University of Cape Town
publishDate	2014
url	http://hdl.handle.net/11427/10668
work_keys_str_mv	AT makhubelabanothilecharityevents thesynthesischaracterizationandreactivityofmetallacycloalkanesandtheirprecursors AT makhubelabanothilecharityevents synthesischaracterizationandreactivityofmetallacycloalkanesandtheirprecursors
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The synthesis, characterization and reactivity of metallacycloalkanes and their precursors

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