Synthesis of Single Isomer Trisubstituted and Tetrasubstituted Olefins from E-β-Chloro-α-Iodo-α,β-Unsaturated Esters and Bergman Cycloaromatizations With and Without a Radical Trapping Agent

Synthesis of Single Isomer Trisubstituted and Tetrasubstituted Olefins from E-β-Chloro-α-Iodo-α,β-Unsaturated Esters and Bergman Cycloaromatizations With and Without a Radical Trapping Agent

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Optimized methods for the regioselective and stereospecific synthesis of both trisubstituted and tetrasubstituted olefins as single isomers from E-β-chloro-α-iodo-α,β-unsaturated esters have been developed from previous work done in the Ogilvie lab. These optimized methods have led to the synthesis...

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Bibliographic Details
Main Author: Pianosi, Anthony
Other Authors: Ogilvie, William W.
Language:en
Published: Université d'Ottawa / University of Ottawa 2011
Subjects:
Bergman cyclization
olefin
alkene
trisubstituted olefins
tetrasubstituted olefins
radical trapping agent
photoisomerization
Online Access:http://hdl.handle.net/10393/20456
http://dx.doi.org/10.20381/ruor-5071

Internet

http://hdl.handle.net/10393/20456
http://dx.doi.org/10.20381/ruor-5071

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