The Tail Wags the Dog: The Far Periphery of the Coordination Environment Manipulates the Photophysical Properties of Heteroleptic Cu(I) Complexes
In this work we show, using the example of a series of [Cu(Xantphos)(NˆN)]+ complexes (NˆN being substituted 5-phenyl-bipyridine) with different peripheral NˆN ligands, that substituents distant from the main action zone can have a significant effect on the physicochemical properties of the system....
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI
2022
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| Subjects: | |
| Online Access: | View Fulltext in Publisher |