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01881nam a2200277Ia 4500 |
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10.1002-cctc.202200288 |
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220630s2022 CNT 000 0 und d |
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|a 18673880 (ISSN)
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|a Monolithic Al2O3 Xerogels with Hierarchical Meso-/Macropore System as Catalyst Supports for Methanation of CO2
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|b John Wiley and Sons Inc
|c 2022
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|a Cylindrical, cm-sized monolithic Al2O3 xerogels with hierarchical meso-/macropore system were prepared by sol-gel synthesis. The influence of both solvent exchange and drying on monolith stability and the resulting pore system was studied following mass and volume of the monolith as well as by porosimetry and electron microscopy. Crack-free drying of the monoliths requires a proper management of drying stress. This is achieved by adjusting the drying rate and solvent exchange procedure applied to the intermediate lyogels. Moreover, mainly through differences in capillary pressure, changing the pore fluid allows an adjustment of the mesopore width from 7.6 nm to 10.5 nm. Neither solvent exchange nor drying affect the macropores, the width of which stays at 1.5 μm. Finally, CO2 methanation over Ni-impregnated Al2O3 monoliths reveals CO2 conversion and CH4 selectivity comparable to an industrial Ni/Al2O3 benchmark catalyst. © 2022 The Authors. ChemCatChem published by Wiley-VCH GmbH.
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|a Aluminum Oxide
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|a CO2 Methanation
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|a Drying
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|a Monoliths
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|a Sol-Gel Synthesis
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|a Solvent Exchange
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|a Abel, K.L.
|e author
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|a Beger, T.
|e author
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|a Gläser, R.
|e author
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|a Kuschel, O.
|e author
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|a Poppitz, D.
|e author
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|a Sundmacher, K.
|e author
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|a Zimmermann, R.T.
|e author
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|t ChemCatChem
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|z View Fulltext in Publisher
|u https://doi.org/10.1002/cctc.202200288
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