Fabrication of CdSe nanoparticles sensitized TiO2 nanotube arrays via pulse electrodeposition for photoelectrochemical application

Solar energy is an alternative sustainable energy resource that can be harvested using photoelectrochemical cell comprised of inorganic sensitized nanostructured oxide semiconductor electrode. In this work, pulse electrodeposition was used to deposit CdSe onto titanium dioxide nanotube arrays (TiO2...

Full description

Bibliographic Details
Main Authors: Ayal, A.K (Author), Chang, S.-K (Author), Holi, A.M (Author), Lim, H.N (Author), Lim, Y.-C (Author), Talib, Z.A (Author), Zainal, Z. (Author)
Format: Article
Language:English
Published: Elsevier Ltd 2018
Subjects:
Online Access:View Fulltext in Publisher
View in Scopus
LEADER 03125nam a2200577Ia 4500
001 10.1016-j.materresbull.2018.05.040
008 220120s2018 CNT 000 0 und d
020 |a 00255408 (ISSN) 
245 1 0 |a Fabrication of CdSe nanoparticles sensitized TiO2 nanotube arrays via pulse electrodeposition for photoelectrochemical application 
260 0 |b Elsevier Ltd  |c 2018 
490 1 |t Materials Research Bulletin 
650 0 4 |a Cadmium compounds 
650 0 4 |a Cdse 
650 0 4 |a CdSe 
650 0 4 |a Charge transfer 
650 0 4 |a Electrochemical cells 
650 0 4 |a Electrochemical deposition 
650 0 4 |a Electrochemistry 
650 0 4 |a Electrodes 
650 0 4 |a Grain boundaries 
650 0 4 |a II-VI semiconductors 
650 0 4 |a Nanoparticles 
650 0 4 |a Nanotubes 
650 0 4 |a Oxide semiconductors 
650 0 4 |a Photoconversion efficiency 
650 0 4 |a Photoelectrochemical 
650 0 4 |a Photoelectrochemical applications 
650 0 4 |a Photoelectrochemical cells 
650 0 4 |a Photoelectrochemical performance 
650 0 4 |a Photoelectrochemicals 
650 0 4 |a Pulse electrochemical deposition 
650 0 4 |a Reduction 
650 0 4 |a Selenium compounds 
650 0 4 |a Semiconductor electrode 
650 0 4 |a Solar energy 
650 0 4 |a TiO2 nanotube 
650 0 4 |a TiO2 nanotubes 
650 0 4 |a Titanium dioxide 
650 0 4 |a Titanium dioxide nanotube array 
650 0 4 |a Yarn 
856 |z View Fulltext in Publisher  |u https://doi.org/10.1016/j.materresbull.2018.05.040 
856 |z View in Scopus  |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048447659&doi=10.1016%2fj.materresbull.2018.05.040&partnerID=40&md5=3435a0e8fc19def2b8f91f27c435a3bb 
520 3 |a Solar energy is an alternative sustainable energy resource that can be harvested using photoelectrochemical cell comprised of inorganic sensitized nanostructured oxide semiconductor electrode. In this work, pulse electrodeposition was used to deposit CdSe onto titanium dioxide nanotube arrays (TiO2 NTAs). TiO2 NTAs are commonly used in the nanostructured photoelectrochemical cells due to their high surface area, fewer interfacial grain boundaries and excellent charge transfer between interfaces. Duty cycle of pulse electrodeposition played an important role in the formation of CdSe nanoparticles. A significant enhancement in the photoelectrochemical performance was observed for the heterostructure of CdSe/TiO2 NTAs. CdSe/TiO2 NTAs prepared at 50% duty cycle exhibited maximum photocurrent of 1.94 mA cm−2 and photoconversion efficiency of 1.18% which was 59 times higher than bare TiO2 NTAs. These results demonstrated that significant enhancement in the photoconversion efficiency could be obtained by incorporating CdSe as sensitizer into the TiO2 nanotube arrays via pulse electrodeposition technique. © 2018 Elsevier Ltd 
700 1 0 |a Ayal, A.K.  |e author 
700 1 0 |a Chang, S.-K.  |e author 
700 1 0 |a Holi, A.M.  |e author 
700 1 0 |a Lim, H.N.  |e author 
700 1 0 |a Lim, Y.-C.  |e author 
700 1 0 |a Talib, Z.A.  |e author 
700 1 0 |a Zainal, Z.  |e author 
773 |t Materials Research Bulletin