Growth mechanisms of MgO nanocrystals via a sol-gel synthesis using different complexing agents

• Main Authors: Kamarudin, N. (Author), Kamarulzaman, N. (Author), Mahat, A.M (Author), Mastuli, M.S (Author), Nawawi, M.A (Author), Rusdi, R. (Author)
• Format: Article
• Language: English
• Published: Springer New York LLC 2014
• Subjects: Complexation sites; Complexing agent; Complexing agents; Crystal growth; Crystallite size; Different structure; Growth mechanisms; Magnesia; MgO; Nanocrystals; Nanostructured materials; Organic acids; Oxalic acid; Simultaneous thermogravimetric analysis; Sol - Gel synthesis; Sol-gel process; Synthesis parameters; Thermal-annealing; Thermogravimetric analysis; X ray diffraction
• Online Access: View Fulltext in Publisher; View in Scopus

 In the preparation of nanostructured materials, it is important to optimize synthesis parameters in order to obtain the desired material. This work investigates the role of complexing agents, oxalic acid and tartaric acid, in the production of MgO nanocrystals. Results from simultaneous thermogravimetric analysis (STA) show that the two different synthesis routes yield precursors with different thermal profiles. It is found that the thermal profiles of the precursors can reveal the effects of crystal growth during thermal annealing. X-ray diffraction confirms that the final products are pure, single phase and of cubic shape. It is also found that complexing agents can affect the rate of crystal growth. The structures of the oxalic acid and tartaric acid as well as the complexation sites play very important roles in the formation of the nanocrystals. The complexing agents influence the rate of growth which affects the final crystallite size of the materials. Surprisingly, it is also found that oxalic acid and tartaric acid act as surfactants inhibiting crystal growth even at a high temperature of 950°C and a long annealing time of 36 h. The crystallite formation routes are proposed to be via linear and branched polymer networks due to the different structures of the complexing agents. © 2014, Mastuli et al.; licensee Springer.