Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates

Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates

AstereodivergentPd/Cucatalyst systemforasymmetric desymmetric alkylation of allylic geminal dicarboxylates has been developed, which was successfully applied to the asymmetric synthesis of β-hydroxycarbonylmotifs bearing a versatile carbon-carbon double bond in an enantio- and diastereodivergent man...

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Bibliographic Details
Main Authors: Gridneva, T. (Author), Huo, X. (Author), Li, G. (Author), Luo, Y. (Author), Sun, Y. (Author), Wu, Y. (Author), Ye, Y. (Author), Zhang, J. (Author), Zhang, W. (Author), Zhao, L. (Author)
Format: Article
Language:English
Published: Chinese Chemical Society 2022
Subjects:
asymmetric allylic substitution
bimetallic catalysis
desymmetrization
Pd/Cu dual catalysis
stereodivergent synthesis
Online Access:View Fulltext in Publisher

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