3-(2-benzothiazolylazo)thenoyltrifluoro acetone and its cu(ii), co(ii), ni(ii) and zn(ii) complexes

The coupling of diazotized 2-aminobenzothiazole with thenoyltrifluoroacetone resulted in the formation of a tridentate ligand (HL). Azo-enol tautomeric form of the compound with intramolecular hydrogen bond is confirmed by spectral and analytical data. Formation of its [CoL2], [NiL2], [CuL(OAc)] and...

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Bibliographic Details
Main Authors: Babu, D.K (Author), Krishnankutty, K. (Author), Malini, P. (Author), Ummathur, M.B (Author)
Format: Article
Language:English
Published: Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma 2021
Subjects:
Online Access:View Fulltext in Publisher
LEADER 01440nam a2200229Ia 4500
001 10.31788-RJC.2021.1436292
008 220427s2021 CNT 000 0 und d
020 |a 09741496 (ISSN) 
245 1 0 |a 3-(2-benzothiazolylazo)thenoyltrifluoro acetone and its cu(ii), co(ii), ni(ii) and zn(ii) complexes 
260 0 |b Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma  |c 2021 
856 |z View Fulltext in Publisher  |u https://doi.org/10.31788/RJC.2021.1436292 
520 3 |a The coupling of diazotized 2-aminobenzothiazole with thenoyltrifluoroacetone resulted in the formation of a tridentate ligand (HL). Azo-enol tautomeric form of the compound with intramolecular hydrogen bond is confirmed by spectral and analytical data. Formation of its [CoL2], [NiL2], [CuL(OAc)] and [ZnL2] complexes with monobasic tridentate coordination is also proposed based on analytical and spectral data. Magnetic studies revealed that Cu(II), Ni(II) and Co(II) complexes are paramagnetic while the Zn(II) chelate is diamagnetic. © 2021, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved. 
650 0 4 |a Azo-enol Form 
650 0 4 |a Benzothiazolylazo Derivative 
650 0 4 |a Metal Complexes 
650 0 4 |a Spectral Studies 
650 0 4 |a Thenoyltrifluoroacetone 
700 1 |a Babu, D.K.  |e author 
700 1 |a Krishnankutty, K.  |e author 
700 1 |a Malini, P.  |e author 
700 1 |a Ummathur, M.B.  |e author 
773 |t Rasayan Journal of Chemistry