Effect of Bi substitution on structural and AC magnetic susceptibility properties of Nd1−xBixMnO3
This study synthesizes the neodymium-based manganites with Bi doping, Nd1−xBixMnO3 (x = 0, 0.25 and 0.50) using the solid-state reaction route. The crystal structural, morphological and magnetic properties were determined using X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR),...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG,
2020
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| Subjects: | |
| Online Access: | View Fulltext in Publisher View in Scopus |
| Summary: | This study synthesizes the neodymium-based manganites with Bi doping, Nd1−xBixMnO3 (x = 0, 0.25 and 0.50) using the solid-state reaction route. The crystal structural, morphological and magnetic properties were determined using X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM) and AC magnetic susceptibility. The Rietveld refinement confirmed that the compounds were in the single-phase orthorhombic structure of the NdMnO3 with Pbnm space group and lattice parameter b increased with doping from 5.5571 (x = 0) to 5.6787 (x = 0.5). FTIR spectra showed that absorption bands were located within the range of 550–600 cm−1, which corresponded to the Mn–O stretching vibration. FESEM exhibited homogenous compound. The AC magnetic susceptibility measurement studies showed a strong antiferromagnetic (AFM) to paramagnetic (PM) transition existed at 76 K, 77 K and 67 K for samples (x = 0, 0.25 and 0.50), respectively. © 2020 by the authors. Licensee MDPI, Basel, Switzerland. |
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| ISBN: | 20734352 (ISSN) |
| ISSN: | 20734352 (ISSN) |
| DOI: | 10.3390/cryst10060521 |