|
|
|
|
LEADER |
01275 am a22001933u 4500 |
001 |
345404 |
042 |
|
|
|a dc
|
100 |
1 |
0 |
|a Pileio, Giuseppe
|e author
|
700 |
1 |
0 |
|a Hill-Cousins, Joseph T.
|e author
|
700 |
1 |
0 |
|a Mitchell, Sam
|e author
|
700 |
1 |
0 |
|a Kuprov, Ilya
|e author
|
700 |
1 |
0 |
|a Brown, Lynda J.
|e author
|
700 |
1 |
0 |
|a Brown, Richard C. D.
|e author
|
700 |
1 |
0 |
|a Levitt, Malcolm H.
|e author
|
245 |
0 |
0 |
|a Long-lived nuclear singlet order in near-equivalent 13c spin pairs
|
260 |
|
|
|c 2012-10-24.
|
856 |
|
|
|z Get fulltext
|u https://eprints.soton.ac.uk/345404/1/ja3089873-1.pdf
|
520 |
|
|
|a Molecules that support 13C singlet states with lifetimes of over 10 min in solution have been designed and synthesized. The 13C2 spin pairs in the asymmetric alkyne derivatives are close to magnetic equivalence, so the 13C long-lived singlet states are stable in high magnetic field and do not require maintenance by a radiofrequency spin-locking field. We suggest a model of singlet relaxation by fluctuating chemical shift anisotropy tensors combined with leakage associated with slightly broken magnetic equivalence. Theoretical estimates of singlet relaxation rates are compared with experimental values. Relaxation due to antisymmetric shielding tensor components is significant.
|
655 |
7 |
|
|a Article
|