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01359 am a22002053u 4500 |
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77825 |
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|a Pruneri, V.
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|a Bonfrate, G.
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|a Kazansky, P.G.
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|a Takebe, H.
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|a Morinaga, K.
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|a Kohno, M.
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|a Kuwasaki, K.
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|a Takeuchi, T.
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|a High second-order optical nonlinearities in thermally poled sol-gel silica
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|c 1999-05.
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|z Get fulltext
|u https://eprints.soton.ac.uk/77825/1/1777.pdf
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|a Silica glass samples prepared by a sol-gel process, the mixture of silica sol for gelation and colloidal silica particles, have been thermally poled in vacuum by continuous high voltage (8-12 kV) at elevated temperature (280°C). High second-order nonlinearities (>1pm/V), located under the anodic surface, have been measured and the values are higher than those obtained in fixed silica glass, poled under the same conditions. A model for thermal poling is suggested which explains the experimental results in sol-gel silica and the difference between thermal poling of sol-gel and fused silica. The granular structure and the boundaries of sol-gel silica seem to play a major role in establishing the electrical properties of the depletion layer during and after poling.
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|a Article
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