Fabrication and optical characterisation of doped germanosilicate fibres

This work assesses the incorporation of dopant ions such as Al<sup>3+</sup>, Ga<sup>3+</sup>, Zr<sup>4+</sup>, Nb<sup>5+</sup>, Ta<sup>5+</sup> and Er<sup>3+</sup> into the core of germanosilicate optical fibres via modified-che...

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Bibliographic Details
Main Authors: Taylor, E.R (Author), Ye, C.C (Author), Ault, B.J (Author), Payne, D.N (Author)
Format: Article
Language:English
Published: 1993-01-01.
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Summary:This work assesses the incorporation of dopant ions such as Al<sup>3+</sup>, Ga<sup>3+</sup>, Zr<sup>4+</sup>, Nb<sup>5+</sup>, Ta<sup>5+</sup> and Er<sup>3+</sup> into the core of germanosilicate optical fibres via modified-chemical-vapour deposition plus solution doping fabrication techniques. We find that highly-charged smaller ions, like Al<sup>3+</sup> and Ta<sup>5+</sup>, behave similarly. These ions are more efficiently incorporated, assist in the incorporation of Er<sup>3+</sup>, and have the same influence on the fluorescence spectra of Er<sup>3+</sup>. The structural role of these ions appear to be their ability to provide nonbridging oxygens around Er<sup>3+</sup>. The waveguide and lasing characteristics of Er<sup>3+</sup> codoped with Ta<sup>5+</sup> are presented.