3,4-Dichlorophenoxyacetate interleaved into anionic clay for controlled release formulation of a new environmentally friendly agrochemical
A new layered organic-inorganic nanohybrid material, zinc-aluminum-3,4-dicholorophenoxyacetate (N3,4-D) in which an agrochemical, 3,4-dichlorophenoxyacetic acid (3,4-D), is intercalated into zinc-aluminum-layered double hydroxide (ZAL), was synthesized by coprecipitation method. A well-ordered nanom...
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Format: | Article |
Language: | English |
Online Access: | View Fulltext in Publisher |
LEADER | 01599nam a2200169Ia 4500 | ||
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001 | 10.1186-1556-276X-8-362 | ||
008 | 220127s2013 CNT 000 0 und d | ||
020 | |a 1556-276X | ||
020 | |a 1931-7573 | ||
245 | 1 | 0 | |a 3,4-Dichlorophenoxyacetate interleaved into anionic clay for controlled release formulation of a new environmentally friendly agrochemical |
490 | 1 | 0 | |t NANOSCALE RESEARCH LETTERS |
856 | |z View Fulltext in Publisher |u https://doi.org/10.1186/1556-276X-8-362 | ||
520 | 3 | |a A new layered organic-inorganic nanohybrid material, zinc-aluminum-3,4-dicholorophenoxyacetate (N3,4-D) in which an agrochemical, 3,4-dichlorophenoxyacetic acid (3,4-D), is intercalated into zinc-aluminum-layered double hydroxide (ZAL), was synthesized by coprecipitation method. A well-ordered nanomaterial was formed with a percentage loading of 53.5% (w/w). Due to the inclusion of 3,4-D, basal spacing expanded from 8.9 in ZAL to 18.7 in N3,4-D. The Fourier transform infrared study shows that the absorption bands of the resulting nanohybrid composed of both the 3,4-D and ZAL further confirmed the intercalation episode. Thermal analysis shows that ZAL host enhances the thermal stability of 3,4-D. Controlled-release experiment shows that the release of 3,4-D in the aqueous media is in the order of phosphate > carbonate > sulfate > chloride. These studies demonstrate the successful intercalation of the 3,4-D and its controlled release property in various aqueous media. | |
700 | 1 | 0 | |a Ghazali, SAISM |e author |
700 | 1 | 0 | |a Hussein, MZ |e author |
700 | 1 | 0 | |a Sarijo, SH |e author |
773 | 1 | 0 | |t NANOSCALE RESEARCH LETTERS |