Unexpected Reaction Pathway of the Alpha-Aminoalkyl Radical Derived from One-Electron Oxidation of <i>S</i>-Alkylglutathiones

Unexpected Reaction Pathway of the Alpha-Aminoalkyl Radical Derived from One-Electron Oxidation of <i>S</i>-Alkylglutathiones

Laser flash photolysis and high-resolution mass spectrometry were used to investigate the mechanism of one-electron oxidation of two <i>S</i>-alkylglutathiones using 3-carboxybenzophenone (3CB) as a photosensitizer. This report indicates an unexpected reaction pathway of the &#945;-a...

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Bibliographic Details
Main Authors: Tomasz Pedzinski, Krzysztof Bobrowski, Bronislaw Marciniak, Piotr Filipiak
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Molecules
Subjects:
<i>s</i>-alkylglutathiones
one-electron oxidation
laser flash photolysis
decarboxylation
Online Access:https://www.mdpi.com/1420-3049/25/4/877

Internet

https://www.mdpi.com/1420-3049/25/4/877

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