Catalyst Speciation during <i>ansa</i>-Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of Zr-Allyl Intermediates <xref rid="fn1-polymers-503797" ref-type="fn">†</xref>

Catalyst Speciation during <i>ansa</i>-Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of Zr-Allyl Intermediates <xref rid="fn1-polymers-503797" ref-type="fn">†</xref>

Catalyst speciation during polymerization of 1-hexene in benzene or toluene solutions of the catalyst precursor SBIZr(&#956;-Me)<sub>2</sub>AlMe<sub>2</sub><sup>+</sup> B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub><sup>&am...

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Bibliographic Details
Main Authors: Valentina N. Panchenko, Dmitrii E. Babushkin, John E. Bercaw, Hans H. Brintzinger
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Polymers
Subjects:
polymerization catalysis
UV-vis spectroscopy
catalyst speciation
zirconocene-allyl cations
de-activation
re-activation
Online Access:https://www.mdpi.com/2073-4360/11/6/936

Internet

https://www.mdpi.com/2073-4360/11/6/936

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