Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters

Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters

The stoichiometric reactions of 8-(2,6-R1-4-R2-anilide)-5,6,7-trihydroquinoline (LH) with AlR3 (R = Me or Et) afforded the aluminum complexes LAlR2 (Al1–Al5,Al1: R1 = iPr, R2 = H, R = Me; Al2: R1 = Me, R2 = H, R = Me; Al3: R1 = H, R2 = H, R = Me; Al4: R1 = Me, R2 = Me, R = Me; Al5: R1 = Me, R2 = Me,...

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Bibliographic Details
Main Authors: Shaofeng Liu, Jie Zhang, Weiwei Zuo, Wenjuan Zhang, Wen-Hua Sun, Hongqi Ye, Zhibo Li
Format: Article
Language:English
Published: MDPI AG 2017-03-01
Series:Polymers
Subjects:
aluminum complexes
crystal structures
ring-opening polymerization
biodegradable polyesters
Online Access:http://www.mdpi.com/2073-4360/9/3/83

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http://www.mdpi.com/2073-4360/9/3/83

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