CARBOXYLATE SUBSTITUTION PATTERN AS STRUCTURAL DIRECTIVE FOR THE FINAL PRODUCTS: SYNTHESIS, STRUCTURE AND PROPERTIES OF [Fe4Ca2O2(μ2-HCCl2COO)10(μ3-HCCl2COO)2(THF)6]

CARBOXYLATE SUBSTITUTION PATTERN AS STRUCTURAL DIRECTIVE FOR THE FINAL PRODUCTS: SYNTHESIS, STRUCTURE AND PROPERTIES OF [Fe4Ca2O2(μ2-HCCl2COO)10(μ3-HCCl2COO)2(THF)6]

A novel hexanuclear iron-calcium-oxo complex has been synthesized and characterized by different physico-chemical methods and X-ray single crystal structural analysis: [Fe4Ca2O2(μ2-HCCl2COO)10(μ3-HCCl2COO)2(THF)6].The molecular structure shows that there are two types of coordination for COO- anions...

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Bibliographic Details
Main Authors: Denis Prodius, Valeriu Mereacre, Maria Gdaniec, Sergiu Shova, Yurii A. Simonov, Nicolae Stanica, Ion Geru, Andrea Caneschi, Constantin Turta
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2008-12-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Iron(III) calcium(II) heterocluster
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/Prodius.pdf

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http://www.cjm.asm.md/sites/default/files/article_files/Prodius.pdf

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