New Oxidovanadium(IV) Complexes with 2,2′-bipyridine and 1,10-phenathroline Ligands: Synthesis, Structure and High Catalytic Activity in Oxidations of Alkanes and Alcohols with Peroxides

New Oxidovanadium(IV) Complexes with 2,2′-bipyridine and 1,10-phenathroline Ligands: Synthesis, Structure and High Catalytic Activity in Oxidations of Alkanes and Alcohols with Peroxides

Reactions of [VCl<sub>3</sub>(thf)<sub>3</sub>] or VBr<sub>3</sub> with 2,2&#8242;-bipyridine (bpy) or 1,10-phenanthroline (phen) in a 1:1 molar ratio in air under solventothermal conditions has afforded polymeric oxidovanadium(IV) four complexes <b>1<...

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Bibliographic Details
Main Authors: Iakov S. Fomenko, Artem L. Gushchin, Pavel A. Abramov, Maksim N. Sokolov, Lidia S. Shul'pina, Nikolay S. Ikonnikov, Maxim L. Kuznetsov, Armando J. L. Pombeiro, Yuriy N. Kozlov, Georgiy B. Shul’pin
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Catalysts
Subjects:
oxidovanadium(IV) complexes
heterocyclic diimines
alkanes
hydrogen peroxide
alkyl hydroperoxides
DFT calculations
reaction mechanism
Fenton mechanism
Online Access:https://www.mdpi.com/2073-4344/9/3/217

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https://www.mdpi.com/2073-4344/9/3/217

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