α-Photooxygenation of chiral aldehydes with singlet oxygen

Organocatalytic α-oxygenation of chiral aldehydes with photochemically generated singlet oxygen allows synthesizing chiral 3-substituted 1,2-diols. Stereochemical results indicate that the reaction in the presence of diarylprolinol silyl ethers is highly diastereoselective and that the configuration...

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Bibliographic Details
Main Authors: Dominika J. Walaszek, Magdalena Jawiczuk, Jakub Durka, Olga Drapała, Dorota Gryko
Format: Article
Language:English
Published: Beilstein-Institut 2019-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
ECD
Online Access:https://doi.org/10.3762/bjoc.15.205